Results 1 to 10 of about 2,931,304 (225)

Physical organic chemistry [PDF]

Beilstein Journal of Organic Chemistry, 2010
Physical organic chemistry – the study of the interplay between structure and reactivity in organic molecules – underpins organic chemistry, and we cannot imagine organic chemistry as a subject without knowledge of mechanism and reactivity. It is sometimes thought that the golden age of ‘physical organic chemistry’ was in the 20th century, when ...
John A. Murphy
doaj   +4 more sources

Organic Chemistry - II

CHIMIA, 2007
Swiss Chemical Society
doaj   +5 more sources

Sustainable radical approaches for cross electrophile coupling to synthesize trifluoromethyl- and allyl-substituted tert-alcohols

iScience, 2021
Summary: Trifluoromethylated molecules have gained privileged recognition among the medicinal and pharmaceutical chemists. Sustainable photoredox- and electrochemical processes were employed to facilitate the relatively less explored radical cross ...
Muhammad Awais Ashraf, Yunjeong Lee, Naila Iqbal, Naeem Iqbal, Eun Jin Cho   +4 more
doaj   +1 more source

Homologation of aryl ketones to long-chain ketones and aldehydes via C–C bond cleavage

iScience, 2022
Summary: Transition metal-catalyzed C–C bond cleavage is a powerful tool for the reconstruction of a molecular skeleton. We report herein the multi-carbon homologation of aryl ketones to long-chain ketones and aldehydes via ligand-promoted Ar−C(O) bond ...
Xing Wang, Ling-Jun Li, Zhen-Yu Wang, Hui Xu, Hui-Xiong Dai   +4 more
doaj   +1 more source

Fluorinated tetrapodal anion transporters

iScience, 2023
Summary: Synthetic anion transporters show potential in treating life-threatening diseases like cystic fibrosis and cancer. However, with increasingly complex transporter architectures designed to control anion binding and transport, it is important to ...
Alexander M. Gilchrist, Xin Wu, Bryson A. Hawkins, David E. Hibbs, Philip A. Gale   +4 more
doaj   +1 more source

Copper-mediated aerobic trifluoromethyltelluration of boronic acids with [Me4N][TeCF3]

iScience, 2022
Summary: A copper-mediated trifluoromethyltelluration of arylboronic acids with [Me4N][TeCF3] using air as an environmental friendly oxidant is presented. The reaction proceeded smoothly under mild conditions in the presence of Cu(OTf)2 and bipyridine to
Jing-Yan Dong, Hao-Nan Wang, Yan-Qian Xie, Cheng-Pan Zhang   +3 more
doaj   +1 more source

Copper-catalyzed oxidative dehydrogenative dearomatization of indole derivatives: A new strategy to construct spirocyclic indolenines

iScience, 2022
Summary: A concise copper-catalyzed oxidative dehydrogenative dearomatization of indole derivatives for the direct synthesis of spirocyclic indolenines containing fluorene and indeno[2,1-b]indole groups has been established.
Junli Chao, Yuanyuan Yue, Ke Wang, Xiaohui Guo, Chunying Sun, Yue Xu, Jianming Liu   +6 more
doaj   +1 more source

Technological Innovations in Photochemistry for Organic Synthesis: Flow Chemistry, High-Throughput Experimentation, Scale-up, and Photoelectrochemistry

Chemical Reviews, 2021
Photoinduced chemical transformations have received in recent years a tremendous amount of attention, providing a plethora of opportunities to synthetic organic chemists. However, performing a photochemical transformation can be quite a challenge because
Laura Buglioni, Fabian Raymenants, Aidan Slattery, Stefan D. A. Zondag, T. Noël   +4 more
semanticscholar   +1 more source

Unanticipated switch of reactivity of isonitrile via N≡C bond scission: Cascade formation of symmetrical sulfonyl guanidine

iScience, 2023
Summary: Unanticipated formation of symmetrical sulfonyl guanidine was observed while treating isonitriles with N,N-dibromoarylsulfonamides in absence of an external amine source.
Debashish Mishra, Sagarika Rajkhowa, Prodeep Phukan   +2 more
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Catalytic Enantiodivergent Michael Addition by Subtle Adjustment of Achiral Amino Moiety of Dipeptide Phosphines

iScience, 2020
Summary: Over the past decades, asymmetric catalysis has been intensely investigated as a powerful tool for the preparation of numerous chiral biologically active compounds.
Huamin Wang, Xiuzheng Li, Youshao Tu, Junliang Zhang   +3 more
doaj   +1 more source