Results 201 to 210 of about 267,449 (298)
Local Solvent Ordering Drives Supramolecular Chirality Inversion
Local solvent organization is shown to govern supramolecular chirality by selecting distinct chiral assembly pathways. A subtle change in water‐DMSO composition reverses the helical sense of a chiral perylene bisimide, while heating induces an irreversible thermal inversion to a more stable enantiomorph.
Triza Pal +4 more
wiley +1 more source
Chirality Transfer to the Magnetic Sublattice in the Hybrid Perovskite (R)-/(S)-3-Fluoropyrrolidinium Copper(II) Chloride. [PDF]
Zhang Z +6 more
europepmc +1 more source
Cobalt‐Catalyzed Asymmetric Construction of Boron Stereocenters With C–N Axial Chirality
A cobalt/Salox‐catalyzed one‐pot annulation enables enantioselective formation of B‐stereogenic centers and C─N axial chirality via C─H/N─H annulation, affording diverse fluorescent products with high stereocontrol and optoelectronic potential. ABSTRACT The efficient construction of boron stereogenic centers alongside axial chirality remains a ...
Subramani Kumaran +5 more
wiley +1 more source
Design Strategies for Developing Chiral Macrocyclic Chelators as a Diagnostic Tool. [PDF]
Zhu Y, Law GL.
europepmc +1 more source
NiH‐Catalyzed Enantio‐ and Regioselective Hydroselenylation of Unactivated Alkenes
Nickel‐hydride‐catalyzed enantio‐ and regioselective hydroselenylation of unactivated alkenes provides access to chiral organoselenium compounds. Enantiodetermining Ni–H insertion followed by single‐electron diselenide activation generates selenyl radical.
Hyung‐Joon Kang +2 more
wiley +1 more source
Deep-ultraviolet chiral interband plasmonics in silicon nanohelices. [PDF]
Kim J +6 more
europepmc +1 more source
Transparent Topological Meta‐Diplexer via Tightly Confined Valley Surface States
An optically transparent topological metasurface supporting tightly confined valley surface states enables robust and flexible wave routing in an ultrathin platform. A compact transparent meta‐diplexer with spatially and spectrally separated channels is realized, while communication experiments verify high‐fidelity signal transmission, opening new ...
Sijie Li +5 more
wiley +1 more source
Light-Imprinted Chirality in Nanomaterials: From Principles to Applications. [PDF]
Jin X, Cortés E, Govorov AO, Ding T.
europepmc +1 more source
External pressure directly tunes the breathing distortion of the kagome lattice in Fe3Sn2, suppressing it near 15 GPa and reversing it at higher pressures. This structural modulation drives a cascade of Lifshitz transitions, reconstructs the Fermi surface, strengthens electronic correlations and carrier localization, and modifies ultrafast electron ...
Marcos Vinicius Gonçalves‐Faria +14 more
wiley +1 more source

