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Mechanical chirality: A chiral catalyst with a ring to it. [PDF]
Nature chemistry, 2016 A chiral [2]rotaxane in which the asymmetry is derived from the way in which the two components are mechanically interlocked — rather than being encoded in the covalent connectivity of the components themselves — has been shown to act as an enantioselective organocatalyst.
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2023
A word $w$ in a free group is called {\em chiral} if there exists a group $G$ such that image of word map corresponding to word $w$ is not closed with respect to inverse. Similarly a group $G$ is said to be {\em chiral} if there exists a word $w$ in free group such that $w$ exhibits chirality on the group $G$. Gordeev et al.
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A word $w$ in a free group is called {\em chiral} if there exists a group $G$ such that image of word map corresponding to word $w$ is not closed with respect to inverse. Similarly a group $G$ is said to be {\em chiral} if there exists a word $w$ in free group such that $w$ exhibits chirality on the group $G$. Gordeev et al.
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On chirality measures and chirality properties
Canadian Journal of Chemistry, 2000It is shown that chiral zeroes are integral to all pseudoscalar functions, and that these functions, and thus the chirality properties that are described by them, are therefore normally unsuitable as chirality measures. The multidimensional nature of chirality properties is explored.
Noham Weinberg, Kurt Mislow
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Current Opinion in Biotechnology, 2003
New strategies are continually being developed for using enzymes to efficiently catalyse the enantioselective synthesis of chiral non-racemic compounds. Alternatives to asymmetric synthesis or kinetic resolution include dynamic kinetic resolution, deracemisation and enantioconvergent transformations.
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New strategies are continually being developed for using enzymes to efficiently catalyse the enantioselective synthesis of chiral non-racemic compounds. Alternatives to asymmetric synthesis or kinetic resolution include dynamic kinetic resolution, deracemisation and enantioconvergent transformations.
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Origins of Life and Evolution of the Biosphere, 1995
The crucial role of homochirality and chiral homogeneity in the self-replication of contemporary biopolymers is emphasized, and the experimentally demonstrated advantages of these chirality attributes in simpler polymeric systems are summarized. The implausibility of life without chirality and hence of a biogenic scenario for the origin of chiral ...
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The crucial role of homochirality and chiral homogeneity in the self-replication of contemporary biopolymers is emphasized, and the experimentally demonstrated advantages of these chirality attributes in simpler polymeric systems are summarized. The implausibility of life without chirality and hence of a biogenic scenario for the origin of chiral ...
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Chiral Mesostructured Inorganic Materials with Optical Chiral Response
Advanced Materials, 2023Shunai Che
exaly
Chiral Recognition inside a Chiral Cucurbituril
Angewandte Chemie, 2007Wei-Hao, Huang +2 more
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Circularly Polarized Light-Enabled Chiral Nanomaterials: From Fabrication to Application
Nano-Micro Letters, 2023Liguang Xu, Hua Kuang, Chuanlai Xu
exaly
Biomolecule-mediated chiral nanostructures: a review of chiral mechanism and application
Advances in Colloid and Interface Science, 2021Yong-Liang Yu, Jianhua Wang
exaly