Theory of Chiral Electrodeposition by Chiral Micro-Nano-Vortices under a Vertical Magnetic Field -1: 2D Nucleation by Micro-Vortices [PDF]
Magnetochemistry, 2022 Remarkable chiral activity is donated to a copper deposit surface by magneto-electrodeposition, whose exact mechanism has been clarified by the three-generation model.
Ryoichi Morimoto +8 more
doaj +6 more sources
Theory of Chiral Electrodeposition by Micro-Nano-Vortexes under a Vertical Magnetic Field-2: Chiral Three-Dimensional (3D) Nucleation by Nano-Vortexes [PDF]
MagnetochemistryThe contributions of magnetohydrodynamic (MHD) vortexes to chiral electrodeposition in a vertical magnetic field were theoretically examined based on the three-generation model of the 2D nucleus, 3D nucleus, and screw dislocation; for the vortexes to ...
Ryoichi Morimoto +7 more
doaj +6 more sources
Epitaxial Electrodeposition of Chiral Films Using Chiral Precursors [PDF]
, 2012 Chiral drugs have played an important role in driving the market for past few decades. Currently, more than half of the drugs marketed are chiral. [1-4] It is well established that chiral drugs often differ in their pharmacological, toxicological and pharmacokinetic properties.
Rakesh Gudavarthy, Elizabeth A.
exaly +4 more sources
Chiral Electrodeposition [PDF]
Electrochemical Society Interface, 2004 Chirality is ubiquitous in Nature. One enantiomer of a molecule is often physiologically active, while the other enantiomer may be either inactive or toxic.
Switzer, Jay A.
exaly +3 more sources
One-Step Electrodeposition of Chiral Plasmonic Gold Nanostructures for Enantioselective Sensing
Electrochemistry, 2022 Chiral plasmonic nanostructures attract much attention because of their potential applications to advanced optical materials and enantioselective sensors. However, the latter has been fabricated on the basis of top-down methods, which take time and cost.
Igseon GU, Takuya ISHIDA, Tetsu TATSUMA
doaj +2 more sources
A smart “Swiss-knife” dithiaaza[7]helicene electroactive tool: adding 3D push-pull features to inherent chirality and film electrodeposition ability [PDF]
Electrochimica ActaA new dithiaaza[7]helicene of remarkably multifaceted nature and functional properties is introduced and studied by comparison with a pool of simpler thia-or azahelicenes and related model molecules. Its helical conjugated backbone endows it with interesting spectroscopic and electrochemical features as well as with powerful inherent chirality.
Clara Baldoli +2 more
exaly +4 more sources
Chirality of magneto-electrodeposited metal film electrodes
Science and Technology of Advanced Materials, 2008 The chiral electrode behaviors of magneto-electrodeposited (MED) Ag and Cu films were examined for the electrochemical reactions of D-glucose, L-glucose and L-cysteine.
Iwao Mogi and Kazuo Watanabe
doaj +4 more sources
Observation of nanoparticle coalescence during core-shell metallic nanowire growth in colloids via nanoscale imaging [PDF]
Nature CommunicationsThe surface morphology and shape of crystalline nanowires significantly influence their functional properties, including phonon transport, electrocatalytic performance, to name but a few.
Dahai Yang +15 more
doaj +2 more sources
Breaking of Odd Chirality in Magnetoelectrodeposition
Magnetochemistry, 2022 Electrodeposition under magnetic fields (magnetoelectrodeposition; MED) can induce surface chirality on copper films. The chiral signs of MED films should depend on the magnetic field polarity; namely, the reversal of the magnetic field causes the ...
Iwao Mogi +3 more
doaj +1 more source
Chirality of electrodeposits grown in a magnetic field [PDF]
Physical Review E, 2004 Electrodeposits grown around a point cathode in a flat, horizontal electrochemical cell have fractal form. When grown in the presence of a perpendicular applied magnetic field, the deposits develop a spiral structure with chirality which reverses on switching the field direction.
T R Ní, Mhíocháin, J M D, Coey
openaire +2 more sources