Enantiospecific electrodeposition of chiral CuO films on Cu(110) from aqueous Cu(II) tartrate and amino acid complexes [PDF]
Electrochimica Acta, 2007 CuO films were anodically electrodeposited onto Cu(1 1 0) single crystals from alkaline solutions of Cu(II) complexed with tartrate, alanine, valine, and glycine. In all cases the films were epitaxial, exhibiting varying amounts of the chiral orientations (1 1 0) and (1 1 0).
Jay Switzer, Eric W Bohannan
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Epitaxial Electrodeposition of Chiral Metal Surfaces on Silicon(643) [PDF]
Journal of the American Chemical Society, 2018 Surfaces of achiral materials exhibit two-dimensional chirality if they lack mirror symmetry. An example is the (643) surface of face-centered-cubic metals such as Au. The (643) and (6̅4̅3̅) surfaces are non-superimposable mirror images of each other.
Qingzhi Chen +2 more
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Enantiospecific Electrodeposition of Chiral CuO Films from Copper(II) Complexes of Tartaric and Amino Acids on Single-Crystal Au(001) [PDF]
Chemistry of Materials, 2004 Chiral films of CuO were electrochemically deposited onto achiral Au(001) using chiral precursors such as tartaric acid and the amino acids alanine and valine to complex the Cu(II). The chirality of the electrodeposited films was dictated by the chiral solution precursor.
Shuji Nakanishi +2 more
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Epitaxial electrodeposition of chiral CuO films from copper(ii) complexes of malic acid on Cu(111) and Cu(110) single crystals [PDF]
Journal of Materials Chemistry, 2011 Chiral films of CuO were anodically electrodeposited onto Cu(111) and Cu(110) single crystals from alkaline solutions of Cu(II) complexed with the malate ion. The chirality of the film was directed by the chiral solution precursor. X-Ray diffraction pole figures and stereographic projections were used to determine the absolute configuration of the ...
Steven Limmer +2 more
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Enantiospecific Electrodeposition of Chiral CuO Films on Single-Crystal Cu(111) [PDF]
Journal of the American Chemical Society, 2003 Epitaxial films of monoclinic CuO have been electrodeposited on single-crystal Cu(111) from solutions containing either (S,S)- or (R,R)-tartrate. X-ray pole figure analysis reveals that the CuO film grown from (S,S)-tartrate exhibits a (1) out-of-plane orientation while the film grown from (R,R)-tartrate has a (11) orientation. Even though CuO does not
Eric W, Bohannan +3 more
openaire +3 more sources
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One-step electrodeposition of the MOF@CCQDs/NiF electrode for chiral recognition of tyrosine isomers
Dalton Transactions, 2020Electrochemical enantiorecognition of tyrosine (Tyr) isomers using a MOF@CCQDs/NiF electrode prepared by electrodepositing a metal–organic framework (MOF) and chiral carbon quantum dots (CCQDs) on Ni foil is reported.
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Electrodeposition of Chiral Polymer–Carbon Nanotube Composite Films
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Inducing enantioselectivity in electrodeposited CuO films by chiral etching
Electrochimica Acta, 2008The enantioselectivity of electrodeposited CuO with a chiral orientation is enhanced if the CuO is first etched in a solution of tartaric acid. Electrochemical quartz crystal microbalance studies show that CuO(111) electrodeposited from l-tartrate etches faster in l-tartaric acid, whereas CuO(111) electrodeposited from d-tartrate etches faster in d ...
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Chiral Electrode Behaviors of Magneto-Electrodeposited Films
ECS Meeting Abstracts, 2008Abstract not Available.
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