Results 121 to 130 of about 2,155,205 (328)

Chiral recognition in bicyclic guanidines

Collection of Czechoslovak Chemical Communications, 2009
A theoretical study of chiral recognition in bicyclic guanidines has been carried out by means of B3LYP/6-31+G(d,p) DFT calculations. A series of complexes between protonated 4,8-dimethyl-1,5,7-triazabicyclodecene (DTBD) and 2,5-disubtituted chiral cyclopentanones have been evaluated for chiral recognition, both in the gas phase and in benzene solution
O'Donovan, D. H., Rozas, Isabel, Blancow, F., Alkorta, Ibon, Elguero, José   +4 more
openaire   +2 more sources

Self‐Assembled Monolayers in p–i–n Perovskite Solar Cells: Molecular Design, Interfacial Engineering, and Machine Learning–Accelerated Material Discovery

Advanced Materials, EarlyView.
This review highlights the role of self‐assembled monolayers (SAMs) in perovskite solar cells, covering molecular engineering, multifunctional interface regulation, machine learning (ML) accelerated discovery, advanced device architectures, and pathways toward scalable fabrication and commercialization for high‐efficiency and stable single‐junction and
Asmat Ullah, Ying Luo, Stefaan De Wolf
wiley   +1 more source

Recent advances in chirality sensing/recognition using supramolecular macrocycles

Supramolecular Materials
Chiral sensing is crucial for understanding and controlling the biological activity of chiral molecule such as carbohydrates, amino acids, and proteins.
Chunhong Liu, Leyong Wang, Zhouyu Wang, Wanhua Wu, Cheng Yang   +4 more
doaj   +1 more source

Photochromic Cholesteric Liquid Crystals via Arylazopyrazole Functionalization of Hydroxypropyl Cellulose

Advanced Materials, EarlyView.
We produce a new derivative of hydroxypropyl cellulose functionalized with arylazopyrazole side chains and demonstrate its photoswitchable behaviors in dilute and concentrated aqueous solutions, ultimately designing a series of photochromic cholesteric materials that can be photopatterned as write‐erase displays.
Simona G. Fine, Nina Hildenhagen, Walter R. Linke, Michael Ryan Hansen, Bart Jan Ravoo, Cécile A. C. Chazot   +5 more
wiley   +1 more source

All‐Optical Reconfigurable Physical Unclonable Function for Sustainable Security

Advanced Materials, EarlyView.
An all‐optical reconfigurable physical unclonable function (PUF) is demonstrated using plasmonic coupling–induced sintering of optically trapped gold nanoparticles, where Brownian motion serves as a robust entropy source. The resulting optical PUF exhibits high encoding density, strong resistance to modeling attacks, and practical authentication ...
Jang‐Kyun Kwak, Changgyun Moon, Hyun‐Bin Yu, Sunkook Kim, Dong‐Hwan Kim   +4 more
wiley   +1 more source

Stoichiometry‐Programmed MXenes via Precursor Engineering for High‐Performance EMI Shielding and Energy Storage

Advanced Materials, EarlyView.
Precursor carbon stoichiometry programs internal strain and oxygen substitution in Ti3AlCxO2‐x, deterministically switching Ti3CxO2‐xTz MXenes between highly aligned 2D nanosheets and spontaneous 1D nanoscrolls. This synthesis‐stage architecture control enables ultrathin X/W‐band EMI shielding with outstanding mass‐normalized performance and bending ...
Jaeeun Park, Ju‐Hyoung Han, Yujin Chae, Mincheal Kim, Juwon Han, Younggeun Jang, Young Ho Jin, Jaewon Wang, Shi‐Hyun Seok, Yeoseon Sim, Zonghoon Lee, EunMi Choi, Soon‐Yong Kwon   +12 more
wiley   +1 more source

Analog Control of Reconfigurable GHz Resonances from Chiral Spin Texture Ensembles

Advanced Materials, EarlyView.
Tunable microwave components ‐ essential for wireless technology ‐ typically require costly, customized nanofabrication. We show that ambient spin texture ensembles (e.g., magnetic skyrmions) in chiral multilayer films can enable reconfigurable microwave resonators.
T. S. Suraj, Jifei Huang, Hui Ru Tan, Jing Zhou, Abhijit Ghosh, Hang Khume Tan, May Inn Sim, Alexander K. J. Toh, Xiaoye Chen, Anjan Soumyanarayanan   +9 more
wiley   +1 more source

Separation of 4-substituted 5-methylpiracetam stereoisomers on polysaccharide-based chiral stationary phases

Journal of Chromatography Open
Monitoring of stereoisomer content in samples containing chiral compounds with multiple chiral centers is an important and challenging task in chiral liquid chromatography.
H. Kažoka, B. Turovska, T. Upmanis
doaj   +1 more source

Anomalous Spin‐Optical Helical Effect in Ti‐Based Kagome Metal

Advanced Materials, EarlyView.
The kagome lattice hosts diverse correlated quantum states, including elusive loop currents. We report spin‐handedness selective signals in CsTi3Bi5, termed the anomalous spin‐optical helical effect, surpassing conventional spin responses. Arising from light helicity coupled to spin‐orbital correlations, this effect provides a sensitive, indirect probe
Federico Mazzola, Wojciech Brzezicki, Chiara Bigi, Armando Consiglio, Luciano Jacopo D'Onofrio, Maria Teresa Mercaldo, Adam Kłosiński, François Bertran, Patrick Le Fèvre, Oliver J. Clark, Mark T. Edmonds, Manuel Tuniz, Alessandro De Vita, Vincent Polewczyk, Jeppe B. Jacobsen, Henrik Jacobsen, Jill A. Miwa, Justin W. Wells, Anupam Jana, Ivana Vobornik, Jun Fujii, Niccolo Mignani, Narges Tarakameh Samani, Alberto Crepaldi, Giorgio Sangiovanni, Anshu Kataria, Tommaso Morresi, Samuele Sanna, Pietro Bonfá, Brenden R. Ortiz, Ganesh Pokharel, Stephen D. Wilson, Domenico Di Sante, Carmine Ortix, Mario Cuoco   +34 more
wiley   +1 more source

Current Switching of Topological Spin Chirality in the van der Waals Antiferromagnet Co1/3TaS2

Advanced Materials, EarlyView.
Spin chirality plays a central role in quantum magnetism, governing spin winding and generating real‐space Berry phases. We propose the intriguing concept of current‐switching spin chirality and demonstrate it via unconventional intrinsic self‐spin‐orbit‐torque in pristine Co1/3TaS2, purely by electrical current and with high energy efficiency.
Kai‐Xuan Zhang, Seungbok Lee, Woonghee Cho, Je‐Geun Park   +3 more
wiley   +1 more source