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Chiral Separations of Pyrethroic Acids Using Cyclodextrin Selectors [PDF]

open access: yesMolecules, 2022
Pyrethroid insecticides are broadly used. They have low toxicity for warm-blooded living creatures, but high toxicity for both insects and fish. Therefore, it is important to reduce the environmental impact of pyrethroids.
Zoltán Juvancz   +4 more
exaly   +4 more sources

Chiral Separations in Preparative Scale: A Medicinal Chemistry Point of View [PDF]

open access: yesMolecules, 2020
Enantiomeric separation is a key step in the development of a new chiral drug. Preparative liquid chromatography (LC) continues to be the technique of choice either during the drug discovery process, to achieve a few milligrams, or to a scale-up during ...
Madalena M M Pinto   +2 more
exaly   +4 more sources

Enantioselective Liquid Chromatographic Separations Using Macrocyclic Glycopeptide-Based Chiral Selectors

open access: yesMolecules, 2021
Numerous chemical compounds of high practical importance, such as drugs, fertilizers, and food additives are being commercialized as racemic mixtures, although in most cases only one of the isomers possesses the desirable properties. As our understanding
István Ilisz   +2 more
exaly   +3 more sources

Direction-specific enhanced diffusion of CO2 in chiral hexagonal boron nitride nanotubes [PDF]

open access: yesNature Communications
To meet performance requirements, the next generation of gas separation membranes will need both high gas permeability and selectivity, attainable if we could coax adsorbates to minimize random Brownian motion and produce direction-specific diffusion ...
Manh-Thuong Nguyen   +4 more
doaj   +2 more sources

Carbene-catalyzed double esterification enables enantioselective conformational self-locking of pillar[5]arenes [PDF]

open access: yesNature Communications
For their chirality, pillar[5]arenes stand out among the most versatile and widely utilized classes of organic host molecules, with numerous applications in materials science and biomedicine.
Vojtěch Dočekal   +6 more
doaj   +2 more sources

Orthogonal assembly of hetero-porous structures by reversible adaptation for efficient isomeric separation [PDF]

open access: yesNature Communications
Isomers separation is a challenging but crucial process in biological and chemical processes. Mixed-matrix membranes (MMMs) combining selective adsorbents within the polymer matrix have the potential for separating isomeric mixtures. However, the limited
Qi Mou   +11 more
doaj   +2 more sources

Polysaccharide- and β-Cyclodextrin-Based Chiral Selectors for Enantiomer Resolution: Recent Developments and Applications

open access: yesMolecules, 2021
Polysaccharides, oligosaccharides, and their derivatives, particularly of amylose, cellulose, chitosan, and β-cyclodextrin, are well-known chiral selectors (CSs) of chiral stationary phases (CSPs) in chromatography, because they can separate a wide range
Cuong Viet Bui   +2 more
doaj   +1 more source

Chiral Recognition for Chromatography and Membrane-Based Separations: Recent Developments and Future Prospects

open access: yesMolecules, 2021
With the rapid development of global industry and increasingly frequent product circulation, the separation and detection of chiral drugs/pesticides are becoming increasingly important. The chiral nature of substances can result in harm to the human body,
Yuan Zhao   +4 more
doaj   +1 more source

Retention indices for naturally-occurring chiral and achiral compounds on common gas chromatography chiral stationary phases

open access: yesResults in Chemistry, 2022
Chiral gas chromatography columns were initially developed for enantiomeric separations, however, they are increasingly being used for routine analyses of natural samples which also include many achiral compounds.
David Alavez-Rosas   +2 more
doaj   +1 more source

Enantioselective Synthesis, Enantiomeric Separations and Chiral Recognition

open access: yesMolecules, 2020
Chirality is a geometric property associated with the asymmetry of tridimensional features that accompanies our daily life at macroscopic as well as microscopic molecular levels [...]
Maria Elizabeth Tiritan   +2 more
doaj   +1 more source

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