The continuing significance of chiral agrochemicals
In the time frame 2018–2023, around 43% of the 35 chiral agrochemicals introduced to the market (herbicides, fungicides, insecticides, acaricides, and nematicides) contain one or more stereogenic centers in the molecule, and almost 69% of them have been marketed as racemic mixtures of enantiomers or stereoisomers.
Peter Jeschke
wiley +1 more source
Domain‐Wall Circulation Gating and Pinning via Compositional Engineering of Cylindrical Nanowires
Cylindrical magnetic nanowires offer a promising platform for future three‐dimensional spintronic devices. By strategically engineering nanometer‐scale chemical modulations, a novel circulation gate is established to control domain wall propagation.
Laura Álvaro‐Gómez +14 more
wiley +1 more source
The baryonic phase in holographic descriptions of the QCD phase diagram
We study holographic models of the QCD temperature-chemical potential phase diagram based on the D3/D7 system with chiral symmetry breaking. The baryonic phase may be included through linked D5-D7 systems. In a previous analysis of a model with a running
Kim, K.-Y. +10 more
core +1 more source
Direct Access to Chiral Piperidines by Enantioselective HAT‐Initiated C(sp3)─H Oxidation
The direct desymmetrization of piperidines is achieved through manganese‐catalyzed enantioselective α‐C(sp3)─H oxidation with hydrogen peroxide, affording versatile chiral N,O‐acetals in good yields and with high enantio‐ and diastereoselectivity. These intermediates provide access to diverse functionalized piperidines with retention of chirality ...
Sethuraman Muthuramalingam +5 more
wiley +2 more sources
[Separation of budesonide enantiomers with amylose-tris-[(S)-1-phenylethyl carbamate] chiral stationary phase and determination of its contents in pharmaceutical preparations]. [PDF]
Huang Y +5 more
europepmc +1 more source
ABSTRACT Therapeutic oligonucleotides (ONs) have rapidly emerged as a novel class of treatments in the pharmaceutical industry, with over 25 medicines approved in the past decade. Ion‐pair reversed‐phase liquid chromatography coupled with mass spectrometry (IP‐RPLC‐MS) is widely used method for ON characterization.
Quang‐Dong Bui +4 more
wiley +1 more source
Simultaneous chiral separation using a combinatorial molecular imprinting phase
Molecular imprinting chiral stationary phase against Cbz-L-Serine (Cbz-L-Ser) and Cbz-L-Alaine (Cbz-L-Ala) were prepared utilizing acrylamide + 2-vinylpyridine as combined basic functional monomers.
Wang, JF +4 more
core
“Smelltronics”—From Gas to Smell Sensing
The emerging field of smelltronics, encompassing sensing technologies for complex volatile organic compounds, holds significant potential for extracting valuable chemical information. It facilitates the noninvasive, real‐time monitoring of humans, food, and the environment.
Takeshi Ono +7 more
wiley +1 more source
Thiooxamide chiral stationary phase for liquid chromatography
A new chiral stationary phase was prepared by reaction of aminopropylsilica with N-(α-phenylethyl)chloroacetamide in the presence of sulfur and used for the high performance liquid-chromatographic separation of 1,1′-binaphthyl-2,2′-diol and Tröger ...
Zavarzin, IV (15513215) +8 more
core
Separation of some tryptophan derivatives using cyclofructan based chiral stationary phase [PDF]
Chiral stationary phase based on R-naphtylethyl derivatized cyclofructan was used for separation of tryptophan derivatives. In normal mode were tested different compositions of mobile phase and minorite modifiers.
Martínková, Monika
core

