Results 261 to 270 of about 67,573 (304)
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Chirality and Chiral Recognition
2009This review summarizes the literature survey on chiral recognition from a theoretical view point. Nevertheless, experimental results in the gas phase are reported when they are relevant for the theoretical calculations. The review is divided into the following sections: general considerations; experiment vs.
Ibon Alkorta, José Elguero
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Chirality Transfer During Alkylation of Chiral Amides.
ChemInform, 2003AbstractFor Abstract see ChemInform Abstract in Full Text.
Takeo, Kawabata +3 more
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Chiral Magnetic Soliton Lattice on a Chiral Helimagnet
Physical Review Letters, 2012Using Lorenz microscopy and small-angle electron diffraction, we directly present that the chiral magnetic soliton lattice (CSL) continuously evolves from a chiral helimagnetic structure in small magnetic fields in Cr(1/3)NbS2. An incommensurate CSL undergoes a phase transition to a commensurate ferromagnetic state at the critical field strength.
Togawa, Y. +9 more
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Dalton Transactions, 2010
We have synthesized and separated the enantiomer pair of chiral cyclotrisiloxanes for the first time. Three-blade propeller-like alignment of three phenyl groups in tri(2-butyl)triphenylcyclotrisiloxane induced a positive Cotton effect with (R)-2-butyl group, and a negative effect with (S)-2-butyl substituent.
Ryoji, Tanaka +2 more
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We have synthesized and separated the enantiomer pair of chiral cyclotrisiloxanes for the first time. Three-blade propeller-like alignment of three phenyl groups in tri(2-butyl)triphenylcyclotrisiloxane induced a positive Cotton effect with (R)-2-butyl group, and a negative effect with (S)-2-butyl substituent.
Ryoji, Tanaka +2 more
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Chirality
ABSTRACTInclusion complexation, hydrogen bonds, π–π interaction, dipole–dipole interaction, and steric hindrance effect all contribute to the enantioseparation ability of cyclodextrin (CD) or CD derivatives. In this work, one native cationic CD chiral stationary phases (SHCDCSP) and four derivatized CD‐CSPs, namely, per(4‐trifluoromethyl ...
Xiaoxuan Li +3 more
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ABSTRACTInclusion complexation, hydrogen bonds, π–π interaction, dipole–dipole interaction, and steric hindrance effect all contribute to the enantioseparation ability of cyclodextrin (CD) or CD derivatives. In this work, one native cationic CD chiral stationary phases (SHCDCSP) and four derivatized CD‐CSPs, namely, per(4‐trifluoromethyl ...
Xiaoxuan Li +3 more
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Mechanical chirality: A chiral catalyst with a ring to it. [PDF]
Nature chemistry, 2016 A chiral [2]rotaxane in which the asymmetry is derived from the way in which the two components are mechanically interlocked — rather than being encoded in the covalent connectivity of the components themselves — has been shown to act as an enantioselective organocatalyst.
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2023
A word $w$ in a free group is called {\em chiral} if there exists a group $G$ such that image of word map corresponding to word $w$ is not closed with respect to inverse. Similarly a group $G$ is said to be {\em chiral} if there exists a word $w$ in free group such that $w$ exhibits chirality on the group $G$. Gordeev et al.
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A word $w$ in a free group is called {\em chiral} if there exists a group $G$ such that image of word map corresponding to word $w$ is not closed with respect to inverse. Similarly a group $G$ is said to be {\em chiral} if there exists a word $w$ in free group such that $w$ exhibits chirality on the group $G$. Gordeev et al.
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On chirality measures and chirality properties
Canadian Journal of Chemistry, 2000It is shown that chiral zeroes are integral to all pseudoscalar functions, and that these functions, and thus the chirality properties that are described by them, are therefore normally unsuitable as chirality measures. The multidimensional nature of chirality properties is explored.
Noham Weinberg, Kurt Mislow
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Current Opinion in Biotechnology, 2003
New strategies are continually being developed for using enzymes to efficiently catalyse the enantioselective synthesis of chiral non-racemic compounds. Alternatives to asymmetric synthesis or kinetic resolution include dynamic kinetic resolution, deracemisation and enantioconvergent transformations.
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New strategies are continually being developed for using enzymes to efficiently catalyse the enantioselective synthesis of chiral non-racemic compounds. Alternatives to asymmetric synthesis or kinetic resolution include dynamic kinetic resolution, deracemisation and enantioconvergent transformations.
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Origins of Life and Evolution of the Biosphere, 1995
The crucial role of homochirality and chiral homogeneity in the self-replication of contemporary biopolymers is emphasized, and the experimentally demonstrated advantages of these chirality attributes in simpler polymeric systems are summarized. The implausibility of life without chirality and hence of a biogenic scenario for the origin of chiral ...
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The crucial role of homochirality and chiral homogeneity in the self-replication of contemporary biopolymers is emphasized, and the experimentally demonstrated advantages of these chirality attributes in simpler polymeric systems are summarized. The implausibility of life without chirality and hence of a biogenic scenario for the origin of chiral ...
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