Multiscale DFT, COSMO‐RS, and molecular dynamics reveal how a biobased piperitone:linoleic acid deep eutectic solvent captures CO2:hydrogen bonding, and apolar domains create nanoscale pockets that selectively adsorb CO2 over N2/O2 at the gas–liquid interface, with efficient thermal desorption enabling sustainable, low‐toxicity carbon‐capture cycles ...
Nuria Aguilar +4 more
wiley +1 more source
Why Choline Chloride? A Comparative Study of Physicochemical Properties and Machine Learning-Driven Insights Into Melting Point Trends. [PDF]
Tian Y +5 more
europepmc +1 more source
Dy2 Schiff Base Single Molecule Magnet Forming a Halogen Bonding Network: Experiment and Theory
A major challenge to improve SMMs is control over phonon‐based relaxation mechanisms, such as the Raman process. We approach this challenge through the incorporation of intermolecular interactions, which can restrict acoustic phonon modes. For this, we engineer the crystal lattice of a Dy2 SMM using halogen bonding and investigate its properties using ...
Jonas Braun +7 more
wiley +1 more source
Choline chloride-hexanoic acid deep eutectic solvent: structure, stability and aggregation behaviour in light rare earth extraction. [PDF]
Mohanta NK, Mishra S, Rajesh P.
europepmc +1 more source
Green reaction media enable chemodivergent oxidation of vanillyl alcohol, selectively affording vanillin or its fully oxidized counterpart, vanillic acid. The use of an earth‐abundant, inexpensive, and nontoxic iron catalyst for the transformation of lignin‐derived alcohol to fine chemicals underscores the sustainability of the process. A low E‐factor (
Rasmiranjan Hota +2 more
wiley +1 more source
Molecular interactions, solubility, and cytotoxic activity of 4‑hydroxycoumarin in choline chloride‑based acidic deep eutectic solvents. [PDF]
Khorsandi M +4 more
europepmc +1 more source
Recent Applications of Propylene Carbonate as a Solvent in Sustainable Organic Synthesis
This review evaluates propylene carbonate (PC) as a non‐toxic green solvent in organic synthesis, highlighting its performance in key reactions including cross‐couplings, asymmetric hydrogenations, peptide synthesis and biocatalysis. Across these processes, PC delivers yields comparable to conventional and alternative green solvents.
Laura G. Aguilar‐Sanchez +1 more
wiley +1 more source
High-performance absorption and regeneration of water vapor by choline chloride-based hydrophilic deep eutectic solvents. [PDF]
Rezaeiyan Z, Keshavarz P.
europepmc +1 more source
Systematic investigation of aliphatic amines identified novel thermally switchable solvents and elucidated the physicochemical properties required for their formation. These solvents facilitated efficient and tunable separations, demonstrating that lower critical solution temperature switchable solvents can be prepared from amine‐acid mixtures that are
Megha Thuruthel Kuriakose +2 more
wiley +1 more source
Insights into Rotational and Translational Dynamics in Mixtures of Ethylene Glycol and Choline Chloride Using Nuclear Magnetic Resonance Techniques. [PDF]
Fraenza CC +3 more
europepmc +1 more source

