Results 151 to 160 of about 407,361 (290)

Hydrophobic Natural Deep Eutectic Solvents for Sustainable CO2 Capture: Molecular Insights From Multiscale Modeling

open access: yesChemPhysChem, Volume 27, Issue 18, 28 September 2026.
Multiscale DFT, COSMO‐RS, and molecular dynamics reveal how a biobased piperitone:linoleic acid deep eutectic solvent captures CO2:hydrogen bonding, and apolar domains create nanoscale pockets that selectively adsorb CO2 over N2/O2 at the gas–liquid interface, with efficient thermal desorption enabling sustainable, low‐toxicity carbon‐capture cycles ...
Nuria Aguilar   +4 more
wiley   +1 more source

Dy2 Schiff Base Single Molecule Magnet Forming a Halogen Bonding Network: Experiment and Theory

open access: yesZeitschrift für anorganische und allgemeine Chemie, Volume 652, Issue 14, 23 September 2026.
A major challenge to improve SMMs is control over phonon‐based relaxation mechanisms, such as the Raman process. We approach this challenge through the incorporation of intermolecular interactions, which can restrict acoustic phonon modes. For this, we engineer the crystal lattice of a Dy2 SMM using halogen bonding and investigate its properties using ...
Jonas Braun   +7 more
wiley   +1 more source

Sustainable Iron Catalysis for Chemodivergent Oxidation of Lignin‐Based Vanillyl Alcohol: Selective Access to Vanillin and Vanillic Acid

open access: yesEuropean Journal of Organic Chemistry, Volume 29, Issue 35, 19 September 2026.
Green reaction media enable chemodivergent oxidation of vanillyl alcohol, selectively affording vanillin or its fully oxidized counterpart, vanillic acid. The use of an earth‐abundant, inexpensive, and nontoxic iron catalyst for the transformation of lignin‐derived alcohol to fine chemicals underscores the sustainability of the process. A low E‐factor (
Rasmiranjan Hota   +2 more
wiley   +1 more source

Recent Applications of Propylene Carbonate as a Solvent in Sustainable Organic Synthesis

open access: yesChemSusChem, Volume 19, Issue 17, 14 September 2026.
This review evaluates propylene carbonate (PC) as a non‐toxic green solvent in organic synthesis, highlighting its performance in key reactions including cross‐couplings, asymmetric hydrogenations, peptide synthesis and biocatalysis. Across these processes, PC delivers yields comparable to conventional and alternative green solvents.
Laura G. Aguilar‐Sanchez   +1 more
wiley   +1 more source

Structure–Property Relationships for n‐Alkylamine and Aliphatic Carboxylic Acid‐Derived Thermomorphic Multiphase Systems

open access: yesChemSusChem, Volume 19, Issue 17, 14 September 2026.
Systematic investigation of aliphatic amines identified novel thermally switchable solvents and elucidated the physicochemical properties required for their formation. These solvents facilitated efficient and tunable separations, demonstrating that lower critical solution temperature switchable solvents can be prepared from amine‐acid mixtures that are
Megha Thuruthel Kuriakose   +2 more
wiley   +1 more source

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