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Catalyst-Controlled Regiodivergent Synthesis of Bicyclo[2.1.1]hexanes via Photochemical Strain-Release Cycloadditions. [PDF]

open access: yesJ Am Chem Soc
Chang YC   +7 more
europepmc   +1 more source
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Cinnamate and cinnamate derivatives in plants

Acta Physiologiae Plantarum, 2016
Cinnamic acid, an ubiquitous alpha beta unsaturated acid, upon hydroxylation yields p-hydroxy cinnamic acid or p-coumarate, a plant mono phenol. Being, precursor for the production of various di (lignans), polyphenols (lignins) and also substituted derivatives, it seems to be an important aromatic chemical in growth and development of plants.
Razia Shuab, Rafiq Lone, K. K. Koul
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Cinnamic aldehyde allergy

Contact Dermatitis, 1975
Positive patch test reactions to 2 % cinnamic aldehyde were obtained from 2.8 % of 34 males and 9.1 % of 55 females. The 9.1 % female reactivity may be traceable to perfumed cosmetics. Simultaneous Jasmin allergy is documented us is the occurrence of alpha‐amyl cinnamic aldehyde in synthetic, Jasmin. The relevance of these reactions is discussed.
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Synthesis of benzyl cinnamate by enzymatic esterification of cinnamic acid

Bioresource Technology, 2015
In this study, lipase catalysis was successfully applied in synthesis of benzyl cinnamate through esterification of cinnamic acid with benzyl alcohol. Lipozyme TLIM was found to be more efficient for catalyzing this reaction than Novozym 435. In order to increase the yield of benzyl cinnamate, several media, including acetone, trichloromethane ...
Yun, Wang   +3 more
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