Monitoring the Switching from Base-on to Base-off Forms of Vitamin B<sub>12</sub> by Natural and Magnetic Circular Dichroism Spectroscopies. [PDF]
Machalska E +9 more
europepmc +1 more source
Dynamic Control of Nucleic Acids Self‐Assembly and Expression Using Photoswitches
We review here the recent progress made in the design of molecular photoswitches, and highlight their implementation for the dynamic control over nucleic acids self‐assembly and expression. ABSTRACT Synthetic nucleic acids have become readily available and now constitute versatile building blocks in materials science—where they can be used to engineer ...
Noemí Nogal +4 more
wiley +1 more source
Chiral population analysis: a real space visualization of X-ray circular dichroism. [PDF]
Freixas VM +4 more
europepmc +1 more source
Solvent Effects on the Conformational Preferences of 2,6‐Pyridylcarboxamide Foldamers
The marked effect of organic solvents and water/methanol mixtures on the conformational preferences of a soluble chiral foldamer has been established in a diverse array of seventeen distinct environments. ABSTRACT The marked influence of organic solvents and water on the conformational preferences of a chiral, soluble 2,6‐pyridylcarboxamide foldamer ...
Alexander R. Davis +5 more
wiley +1 more source
Liquid-Phase Exfoliated 2D Nanomaterials for Enhanced Vibrational Circular Dichroism of Chiral Molecules. [PDF]
Ballance AT +5 more
europepmc +1 more source
A sustainable route to photoresponsive molecular systems is achieved using the bio‐based flavanone (‐)‐isolonchocarpin from Tephrosia vogelii. Through McMurry homocoupling and light‐driven 6‐π‐electrocyclization, an overcrowded alkene and a fluorescent O‐heterocyclic phenanthrene are synthesized.
Deryl H. Limawan +8 more
wiley +1 more source
Circular Dichroism and Multiphoton Circularly Polarized Luminescence Switching Using a Bis-perylene Diimide Macrocycle. [PDF]
Penty SE +8 more
europepmc +1 more source
Helical Folding of Abiotic Chiral Poly(phosphodiester)s
Design and structural analysis of a new class of phosphodiester foldamers are presented. These oligomers that fold into single helical architecture showed length and temperature stability dependence comparable to DNA duplexes. ABSTRACT Functions of biomolecules are intimately linked to their structures which result from the folding of a linear sequence
Ranajit Barman +3 more
wiley +1 more source
Circular dichroism spectroscopy reveals multiple phytochrome photoproducts in equilibrium. [PDF]
Rockwell NC, Lagarias JC.
europepmc +1 more source
Asymmetric Diphosphane Dioxides With A–π–A–π’–D Scaffolds for High‐Purity Deep‐Blue Luminescence
Diphosphane dioxide‐based luminophores with donor–π–acceptor– π’–acceptor scaffold enable efficient deep‐blue emission from tunable charge‐transfer states affording high photoluminescence up to 95%. OLEDs reach EQE 4.9%, aided by triplet–triplet annihilation, highlighting a practical route to high‐performance blue emitters.
Eetu Hakkarainen +10 more
wiley +1 more source

