Polyproline: A Synthetic Polypeptide With Unique Properties
Poly‐L‐proline is a unique polypeptide distinguished by its well‐defined secondary structures and unusual thermal behavior. This mini review highlights recent advances in the synthesis of poly‐L‐proline by N‐carboxyanhydride (NCA) polymerization, the formation of structurally defined architectures and nanostructures, and emerging strategies that ...
Rosanna Le Scouarnec +3 more
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Spectroscopy and Conformer-Selective Photoelectron Circular Dichroism of Chiral Molecules. [PDF]
Nahon L, Zehnacker A.
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Guidelines for Comparing Circular Dichroism Spectroscopy and Molecular Dynamics Simulations for Biomolecules. [PDF]
Campus C +5 more
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The cobalt(II) bis(trifluoroacetylcamphorate) scaffold exhibits versatile coordination chemistry with solvent‐driven ligand exchange and geometrical rearrangements, associated with unique chiroptical properties. Microcrystalline suspension of [Co(tfc)2(CH3CN)2] revealed the largest VCD dissymmetry factor ever reported (g ≈ 0.2 at 1600 cm−1), arising ...
Gianmarco Papi +4 more
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Rapid Quantitative Determination of Enantiomeric Excess by Vibrational Circular Dichroism Using Noise Based Spectral Selection. [PDF]
Jackson AM, Bows JR, Nash GR.
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Induced Circular Dichroism From the Binding of Achiral Bivalent Ligands to Transthyretin. [PDF]
Wood S +7 more
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pH‐Driven Actuation of Unmodified DNA Origami Rectangles
Unmodified DNA origami rectangles exhibit a reversible transition between planar and tubular states driven by near‐neutral pH changes. This behavior arises from crossover‐mediated mechanical coupling of overwound DNA and extends to dimers and nanoribbons, enabling the formation of nanotube architectures without added motifs or chemical modification ...
Diego A. Uehara +4 more
wiley +2 more sources
Chiral Nonlinear Enhancement with Opposite Circular Dichroism Empowered by Dual Bound States in the Continuum. [PDF]
Liu X, Wang L, Meng H.
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Marinocyclins, polycationic macrocyclic depsipeptides, were discovered by genome mining from the marine coral‐derived bacterium Aquimarina megaterium. The compounds have broad‐spectrum activity against gram‐positive and gram‐negative ESKAPE bacteria.
Clara Chepkirui +9 more
wiley +2 more sources
Angularly Tunable Circular Dichroism in a Bilayer Plasmonic Metasurface via Interlayer Coupling. [PDF]
Asefa SA, Kuiri B, Lee D.
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