Decoupling Redox Potentials and Excited State Energies in Substituted Chromium(III) Chromophores
Redox and excited state properties of organic and precious metal CT photocatalysts are strongly entangled. In contrast, redox potentials of polypyridine chromium(III) complexes, that feature purely metal‐centered SF states, are selectively tuned by incremental substituent effects of the CF3 group, while excited state energies and lifetimes remain ...
Steven Sittel +6 more
wiley +1 more source
Chiral manganese halide isomers: decoding the spatial stacking effect on second-harmonic generation circular dichroism. [PDF]
Li J +9 more
europepmc +1 more source
ABSTRACT The rational design of hybrid nanomaterials with precisely controlled properties remains a central challenge in materials science. While atomically precise gold nanoclusters (Au‐NCs) offer molecule‐like control over a metallic core, tuning their optoelectronic behavior via surface engineering is often empirically driven.
Santiago Rodriguez +15 more
wiley +1 more source
Systematic mapping of altermagnetic magnons by resonant inelastic X-ray circular dichroism. [PDF]
Biniskos N +6 more
europepmc +1 more source
5‐Substituted 2‐(naphthalen‐2‐yl)‐4H‐chromen‐4‐ones are reported as a novel class of highly potent and selective triplex DNA ligands. These ligands induce triplex formation at submicromolar concentrations and inhibit enzymatic activity via ligand‐mediated triplex formation.
Nghia Tran +4 more
wiley +1 more source
Tunable Plasmonic Circular Dichroism of Hierarchical Chiral Assemblies. [PDF]
Trazo JG +9 more
europepmc +1 more source
C‐Terminal Nucleobase Modification Amplifies Peptide‐Mediated Liposome Fusion
Let's come together right now. Cationic peptides are known to promote aggregation of negatively charged liposomes through electrostatic interaction. The process is reversible: once neutrality is achieved, liposomes disaggregate. Here, we demonstrate that end‐capping peptides with nucleobases turns the process into irreversible fusion.
Laura Morbiato +4 more
wiley +1 more source
Experimental control system of the X-ray magnetic circular dichroism endstation at Hefei Light Source-II. [PDF]
Kong A +5 more
europepmc +1 more source
Synthesis and Characterization of Carbazole‐Containing Aza[7]helicenes
Double ortho fusion led to different aza[7]helicene frameworks showing strong acidochromic behavior, singlet excited energies being more than twice the triplet energy, and high racemization barriers, allowing chiral resolution and ECD measurements. ABSTRACT Azahelicenes have attracted significant interest due to their intrinsic axial chirality and ...
Inka Marten +2 more
wiley +1 more source
A workflow to define structural classes and classify nucleic acids circular dichroism spectra. [PDF]
Mosca K +5 more
europepmc +1 more source

