Results 171 to 180 of about 653,628 (283)

Extending El Sayed's Rule by 1(n,π*)–3(n,π*) Rotation via Intramolecular Secondary Interaction Enables Room‐Temperature Circularly Polarized Phosphorescence in Solution

Angewandte Chemie, EarlyView.
Weak but skilled: Our results highlight the crucial role of intramolecular secondary interactions to induce an efficient ISC between formally identical 1(n,π*) and 3(n,π*) states in chiral thionated phthalimide derivatives. This unprecedented type of inter‐system crossing (ISC) extends the usual thinking of the El‐Sayed principle and enables the ...
Oscar Charpentier, Marie Guesdon, Catherine Demangeat, Maher Hojorat, Joseph Young, Emrys W. Evans, Vincent Dorcet, Nicolas Galland, Denis Jacquemin, Ludovic Favereau   +9 more
wiley   +2 more sources

Deciphering the Function and Structure of PA1216 as an S-Adenosyl-l-Methionine Binding Protein Using Differential Scanning Fluorimetry and Circular Dichroism. [PDF]

Protein Sci
Fruitwala AM, Tiszler JX, Watson D, Sinha M, Davis TD.   +4 more
europepmc   +1 more source

Ein portalpräorganisiertes Cucurbit[7]uril‐Ruthenium‐Konjugat ermöglicht motivselektive Proteindetektion

Angewandte Chemie, EarlyView.
Die gezielte Veränderung der Erkennungsumgebung am Portal von Cucurbit[7]uril (CB7) wandelt einen Wirt ohne intrinsisches optisches Signal in einen motivselektiven photolumineszenten Rezeptor um. Das am Portal vororganisierte CB7‐Rubpy‐Konjugat zeigt Änderungen der Zugänglichkeit aromatischer Motive unmittelbar an und ermöglicht dadurch die optische ...
Patrick Gruhs, Albert Kraft, Vahideh Mahram, Marco Neumaier, Papri Chakraborty, Emily Janz, Maria Vittoria Balli, Pierre Picchetti, Luca Prodi, Manfred Kappes, Frank Biedermann   +10 more
wiley   +1 more source

An X‑Shaped Chiral Non‑Fullerene n‐Type Semiconductor: Application in Perovskite Solar Cells and Chirality‑Induced Spin Selectivity

Angewandte Chemie, EarlyView.
A highly electron‑accepting derivative of cyclobisbiphenylenecarbonyl (CBBC‐TIC) is reported. CBBC‐TIC functions as an electron‐transport layer for perovskite solar cells, achieving a power conversion efficiency of 20.6%. Furthermore, the enantiomers of CBBC‐TIC exhibited spin‐selective electron transport with high enantiospecific magnetic conductance ...
Yuki Sakamoto, Koki Otsuka, Kuraudo Ishihara, Shuang Li, Ai Shimazaki, Megumi Haramatsu, Junichiro Hirano, Juntaro Nogami, Hiroshi Shinokubo, Hiroki Uratani, Hironori Kaji, Fumitaka Ishiwari, Akinori Saeki, Tomoya Nakamura, Atsushi Wakamiya, Norihito Fukui   +15 more
wiley   +2 more sources

Chiral HPLC Separation of Phosphonothrixin and Phosphonate Derivatives and Electronic Circular Dichroism Characterization of the Isolated Enantiomers. [PDF]

Electrophoresis
Maalouf M, Knab M, Gessner L, Engelhardt M, Friedrich S, Gross H, Boeckler F, Hughes CC, Lämmerhofer M.   +8 more
europepmc   +1 more source

Maximized Circular Dichroism induced by Geometrical Parameters in Twisted Layered Chiral Metamaterials

, 2019
We have studied twisted layered chiral metamaterials (TLCMs) which have three twisted-layers with C4-symmetric unit cell. Chiral metamaterials which exhibit broken mirror symmetry have the potential to be used for many sensing applications. However, most
RHO, JUNSUK, YANG, YOUNGHWAN
core  

Element-Specific Sensitivity of Lanthanoid Ions to Chiral Crystal Fields in K3[Ln2(NO3)9] Probed by 4f-4f Circular Dichroism. [PDF]

Inorg Chem
Inomata Y, Mochizuki C, Kida T.
europepmc   +1 more source

Transfer-Matrix Framework for Modeling Mid-Infrared Vibrational Circular Dichroism Spectra. [PDF]

Anal Chem
Utyushev A, Rasskazov IL, Phal Y.
europepmc   +1 more source

Induced Photoelectron Circular Dichroism as a Probe for Distinguishing Diastereotopic Lone Electron Pairs. [PDF]

Angew Chem Int Ed Engl
Rouquet E, Lepère V, Garcia GA, Nahon L, Vuilleumier R, Zehnacker A.   +5 more
europepmc   +1 more source

Angle-Dependent Terahertz Circular Dichroism and Full-Space Polarization Manipulation via Extrinsic Chiral Metasurfaces. [PDF]

Nanomaterials (Basel)
Wan M, Shen J, Xu H, Ding J, Chen C, Dong Q, Lv Y, Liu L, Luo L, Tang T, Li J, Yao J.   +11 more
europepmc   +1 more source