Results 251 to 260 of about 413,042 (378)

Regioselective Hydration of Terpenes with Cofactor‐Independent Carotenoid 1,2‐Hydratase

open access: yesAngewandte Chemie, EarlyView.
This study reveals a highly regioselective and cofactor‐independent enzymatic approach to terpene and terpenoid hydration using a carotenoid 1,2‐hydratase from Rubrivivax gelatinosus. Beyond detailing reaction optimization strategies, an extensive substrate scope, and scale‐up potential, it explores mutagenesis and structural modeling to identify key ...
Philip Horz   +6 more
wiley   +2 more sources

Biochemical Studies of a Cyanobacterial Halogenase Support the Involvement of a Dimetal Cofactor. [PDF]

open access: yesBiochemistry
Wang ML   +5 more
europepmc   +1 more source

4'-Phosphopantetheine, a Cofactor Bound to Guanosine Triphosphate-dependent Acyl Coenzyme A Synthetase

open access: hybrid, 1970
Carlo Riccardo Rossi   +4 more
openalex   +1 more source

Redox‐ and NIR‐Active Iron(III) Triradicals as Catalysts for Radical Polymerization of Acrylamides and Methacrylates

open access: yesAngewandte Chemie, EarlyView.
A redox‐active low‐spin Fe(III)‐triradical complex was isolated in good yield and utilized as a catalyst for radical polymerization of acrylamides and methacrylates at ambient conditions. Abstract Two unprecedented redox‐active, low‐spin Fe(III)‐triradical complexes, [Fe(III)(SS‐NHC═S•−)3]·NHC═S (1·NHC═S; E═S) and [Fe(III)(SS‐NHC═Se•−)3] (2; E═Se) have
Sujit Das   +11 more
wiley   +2 more sources

Transitioning enzyme catalysis towards photocatalysis. [PDF]

open access: yesPhilos Trans A Math Phys Eng Sci
Scrutton N, Hay S, Heyes D.
europepmc   +1 more source

Engineered C–N Lyases for Stereoselective Synthesis of Tertiary Amines

open access: yesAngewandte Chemie, EarlyView.
EDDS lyase was subjected to iterative cycles of site‐saturation mutagenesis and screened for increased activity for the addition of 2‐((methylamino)methyl)aniline to fumarate. The final mutant, EDDS lyase CEA, accepts various N‐methyl‐1‐phenylmethanamines derivatives, yielding N,N‐disubstituted L‐aspartic acids, as well as several ortho‐substituted ...
Laura Bothof   +4 more
wiley   +2 more sources

Fortification of FeS Clusters Reshapes Anaerobic CO Dehydrogenase into an Air‐Viable Enzyme Through Multilayered Sealing of O2 Tunnels

open access: yesAngewandte Chemie, EarlyView.
Fortification of FeS clusters in Ni─Fe CO dehydrogenase (Carboxydothermus hydrogenoformans) reshapes this anaerobic enzyme into an air‐viable variant through multilayered O2 tunnel sealing. The engineered enzyme retains structural integrity and catalytic efficiency in ambient air, offering a practical solution for industrial CO/CO2 bioconversion ...
Suk Min Kim   +9 more
wiley   +2 more sources

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