Results 251 to 260 of about 413,042 (378)
Biosynthesis of the iron-molybdenum cofactor and the molybdenum cofactor in Klebsiella pneumoniae: effect of sulfur source [PDF]
Rodolfo A. Ugalde+3 more
openalex +1 more source
Regioselective Hydration of Terpenes with Cofactor‐Independent Carotenoid 1,2‐Hydratase
This study reveals a highly regioselective and cofactor‐independent enzymatic approach to terpene and terpenoid hydration using a carotenoid 1,2‐hydratase from Rubrivivax gelatinosus. Beyond detailing reaction optimization strategies, an extensive substrate scope, and scale‐up potential, it explores mutagenesis and structural modeling to identify key ...
Philip Horz+6 more
wiley +2 more sources
Biochemical Studies of a Cyanobacterial Halogenase Support the Involvement of a Dimetal Cofactor. [PDF]
Wang ML+5 more
europepmc +1 more source
A redox‐active low‐spin Fe(III)‐triradical complex was isolated in good yield and utilized as a catalyst for radical polymerization of acrylamides and methacrylates at ambient conditions. Abstract Two unprecedented redox‐active, low‐spin Fe(III)‐triradical complexes, [Fe(III)(SS‐NHC═S•−)3]·NHC═S (1·NHC═S; E═S) and [Fe(III)(SS‐NHC═Se•−)3] (2; E═Se) have
Sujit Das+11 more
wiley +2 more sources
Transitioning enzyme catalysis towards photocatalysis. [PDF]
Scrutton N, Hay S, Heyes D.
europepmc +1 more source
Engineered C–N Lyases for Stereoselective Synthesis of Tertiary Amines
EDDS lyase was subjected to iterative cycles of site‐saturation mutagenesis and screened for increased activity for the addition of 2‐((methylamino)methyl)aniline to fumarate. The final mutant, EDDS lyase CEA, accepts various N‐methyl‐1‐phenylmethanamines derivatives, yielding N,N‐disubstituted L‐aspartic acids, as well as several ortho‐substituted ...
Laura Bothof+4 more
wiley +2 more sources
Nickel-Dithiolene Cofactors as Electron Donors and Acceptors in Protein Hosts. [PDF]
Polycarpou G, Skourtis SS.
europepmc +1 more source
Fortification of FeS clusters in Ni─Fe CO dehydrogenase (Carboxydothermus hydrogenoformans) reshapes this anaerobic enzyme into an air‐viable variant through multilayered O2 tunnel sealing. The engineered enzyme retains structural integrity and catalytic efficiency in ambient air, offering a practical solution for industrial CO/CO2 bioconversion ...
Suk Min Kim+9 more
wiley +2 more sources
De novo biosynthesis of taxifolin in yeast peroxisomes. [PDF]
Wu Q, Chen R, Zhang L.
europepmc +1 more source