Results 201 to 210 of about 10,869,649 (341)

Tailoring Amine Substitution in Fluorene and Dibenzothiophene: A Molecular Strategy for Ultralong Organic Phosphorescence

open access: yesAdvanced Optical Materials, EarlyView.
Tailored amine substitution in fluorene and dibenzothiophene derivatives enables systematic control of excited‐state properties and triplet population. Combined photophysical studies, TD‐DFT calculations and time‐resolved EPR reveal how charge‐transfer character, sulfur‐induced spin–orbit coupling and triplet manifold engineering cooperate to promote ...
Francesco Ruighi   +10 more
wiley   +1 more source

Regioselective π‐Extension of Helical PAHs: Tuning Energy Gaps and Excited‐State Dynamics Directed by Clar's Sextet Migration

open access: yesAdvanced Optical Materials, EarlyView.
Central and terminal ring fusions of per‐peri‐perbenzo[7]helicene (PB[7]H) yield novel helical polycyclic aromatic hydrocarbons (HPAHs). The migration of Clar's aromatic sextets governs the inner‐rim stiffness. This topology‐directed strategy bridges the discrete optical gaps of homologous series. Transition moment density (TMD) analysis visualizes the
Zhibo Liu   +3 more
wiley   +1 more source

Revealing Mechanofluorochromism and Intricate Long‐lived Decay Pathways in Keto‐Coumarin‐Based Molecular Crystals

open access: yesAdvanced Optical Materials, EarlyView.
Donor–acceptor organic emissive materials show great promise in cutting‐edge optical applications. Herein, the photophysical properties of two keto‐coumarin organic materials are studied in detail. Both show mechanofluorochromism, but a diphenylamine donor derivative exhibits intricate decay pathways in the crystal form, including decays ranging from ...
Peter W. McDonald   +6 more
wiley   +1 more source

Gain Narrowing in Low‐Dimensional PEA:CsPbBr3: Superfluorescence versus Amplified Spontaneous Emission

open access: yesAdvanced Optical Materials, EarlyView.
Superfluorescence is a cooperative emission process not scaling with sample volume. Amplified spontaneous emission is a collective process scaling with sample volume and is enhanced by waveguiding. Both manifest in a narrow emission peak. Choosing the right substrate suppresses waveguiding and demonstrates that the emission feature observed in PEA ...
Pirmin Tischler   +10 more
wiley   +1 more source

Localized Ion Irradiation Enables Topography‐Free High‐Tc Superconducting Metamaterials

open access: yesAdvanced Optical Materials, EarlyView.
A topography‐free oxygen ion‐irradiation strategy is demonstrated for patterning superconducting YBCO terahertz metamaterials without physical material removal. The approach preserves film integrity while enabling large spectral tunability, ultrafast optical modulation, and dual‐band resonance control, providing a scalable platform for low‐loss ...
Teng Chen Ietro Pang   +5 more
wiley   +1 more source

Electrically Reconfigurable Optical Initialization of Spin Valley Polarization in Monolayer WS2 Enabled by Switchable Dual‐Mode Liquid Crystal Lasers

open access: yesAdvanced Optical Materials, EarlyView.
This work presents an electrically controllable approach to spin–valley polarization in monolayer WS2 by integrating it with a dual‐mode liquid crystal laser. Applying an external field triggers phase transitions that switch the laser emission between helicity‐defined band‐edge lasing and unpolarized random lasing.
Yu‐Chuan Tsao   +3 more
wiley   +1 more source

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