Results 141 to 150 of about 6,725,229 (312)

Reversible Hydrogen Storage in Solid‐State Reaction Derived Core‐Shell NaBH4@Ni Nanocubes

Advanced Energy & Sustainability Research
The method to synthesize high‐capacity complex hydride nanostructures, such as borohydrides, decorated with metallic shells has surfaced as an attractive approach for enabling reversible hydrogen storage.
Muhammad Saad Salman, Kondo-Francois Aguey-Zinsou   +1 more
doaj   +1 more source

Shedding Light on Synthetic Autocatalysis: From Conventional Closed‐Shell Chemistries to Overlooked Open‐Shell Occurrences

Chemistry – A European Journal, EarlyView.
Why add another catalyst when the product itself holds the power to catalyze its own formation? Autocatalysis in synthetic chemistry enhances reaction efficiency and uncovers novel catalytic behavior across both closed‐shell and open‐shell systems, expanding reactivity and enabling innovative design strategies.
Jaspreet Kaur, Joshua P. Barham
wiley   +1 more source

Molecular hydrogen in the N-doped LuH3 system as a possible path to superconductivity

Nature Communications
The discovery of ambient superconductivity would mark an epochal breakthrough long-awaited for over a century, potentially ushering in unprecedented scientific and technological advancements. The recent findings on high-temperature superconducting phases
Cesare Tresca, Pietro Maria Forcella, Andrea Angeletti, Luigi Ranalli, Cesare Franchini, Michele Reticcioli, Gianni Profeta   +6 more
doaj   +1 more source

Methyl on the Bridge: 2‐Methyl Propellane as Precursor for 1,3‐Substituted 2‐Methylated Bicyclo[1.1.1]Pentanes

Chemistry – A European Journal, EarlyView.
The synthesis of 2‐methyl propellane and its conversion to various 1,2‐ and 1,2,3‐di‐ and trisubstituted bicyclopentanes is reported. Abstract Bicyclo[1.1.1]pentanes (BCPs) have emerged as isosteric replacements for mono‐ and para‐substituted benzene rings in medicinal and materials applications, involving substitution at the BCP bridgehead (1,3 ...
Sean R. Verschaeve, Mariana Gomes Manso, Tibo Van Eeckhoorn, Mark E. Light, Bruno Linclau   +4 more
wiley   +1 more source

Protonation‐Induced Electron Density Redistribution Facilitates Aggregation in PNNP Dicopper Hydride Complexes

Chemistry – A European Journal, EarlyView.
Copper(I) hydride complexes often exhibit diverse aggregation behavior that can profoundly influence their structure and reactivity. In this study we use a combined experimental and computational approach to identify key structural an electronic factors that govern aggregation in PNNP dicopperhydride complexes.
Roel Laurentius Maria Bienenmann, Chattawat Thangsrikeattigun, Alexandra Julia Schanz, Martin Lutz, Mu‐Hyun Baik, Daniël Laurens Johannes Broere   +5 more
wiley   +1 more source

Superhalogens as Building Blocks of Complex Hydrides for Hydrogen Storage [PDF]

, 2016
A. K. Srivastava, N. Misra
semanticscholar   +1 more source

Synthesis of Dithienylcycloalkene Molecular Switches Enabled by a Bench‐Stable Ti‐Complex

Chemistry – A European Journal, EarlyView.
Herein we report a set of cycloalkene‐bridged DTEs with ring sizes ranging from 4‐ to 7‐membered rings. The synthesis of these analogs was performed via a key McMurry coupling step, which was enabled by a practical, bench‐stable Ti(IV)‐complex. Remarkably, it is shown that the strained cyclobutene bridge outperforms other rings, even the most commonly ...
Marcell M. Bogner, Márton Hegedűs, Péter P. Kalapos, Attila Kunfi, Gábor London   +4 more
wiley   +1 more source

Mg2FeH6-based nanocomposites with high capacity of hydrogen storage processed by reactive milling

Materials Research, 2012
The compound Mg2FeH6 was synthesized from a 2Mg-Fe mixture in a single process through high-energy ball milling under hydrogen atmosphere at room temperature. The complex hydride was prepared from Mg powder and granulated or powdered Fe using a planetary
Alexandre Augusto Cesario Asselli, Alberto Moreira Jorge Junior, Tomaz Toshimi Ishikawa, Walter José Botta Filho   +3 more
doaj  

Carbonyl(h5-Cyclopentadienyl)(tetrafluoroborato)molybdenum and tungsten complexes [PDF]

, 1989
Beck, Wolfgang, Schloter, Klaus, Sünkel, Karlheinz, Urban, Günter   +3 more
core   +2 more sources

Synthesis and Isolation of Bismuth Scorpionate Complexes: Toward Bond Activation via Bismuth‐Ligand Cooperation

Chemistry – A European Journal, EarlyView.
ABSTRACT Over the past twenty years, main group chemistry has significantly expanded its scope to include reactivities once considered the exclusive domain of transition metals. Among the emerging concepts, element‐ligand cooperation has proven to be a powerful strategy for enabling bond activation reactions but remains relatively unexplored for ...
Lennart Hensle, Viktoria H. Gessner
wiley   +1 more source