Results 161 to 170 of about 31,033 (331)

Light Weight Complex Metal Hydrides for Reversible Hydrogen Storage

, 2021
Sesha S. Srinivasan, Luis Miguel Rivera Gavidia, Diego Escobar, Elias Stefanakos   +3 more
openalex   +2 more sources

Protonation‐Induced Electron Density Redistribution Facilitates Aggregation in PNNP Dicopper Hydride Complexes

Chemistry – A European Journal, EarlyView.
Copper(I) hydride complexes often exhibit diverse aggregation behavior that can profoundly influence their structure and reactivity. In this study we use a combined experimental and computational approach to identify key structural an electronic factors that govern aggregation in PNNP dicopperhydride complexes.
Roel Laurentius Maria Bienenmann, Chattawat Thangsrikeattigun, Alexandra Julia Schanz, Martin Lutz, Mu‐Hyun Baik, Daniël Laurens Johannes Broere   +5 more
wiley   +1 more source

Synthesis of Dithienylcycloalkene Molecular Switches Enabled by a Bench‐Stable Ti‐Complex

Chemistry – A European Journal, EarlyView.
Herein we report a set of cycloalkene‐bridged DTEs with ring sizes ranging from 4‐ to 7‐membered rings. The synthesis of these analogs was performed via a key McMurry coupling step, which was enabled by a practical, bench‐stable Ti(IV)‐complex. Remarkably, it is shown that the strained cyclobutene bridge outperforms other rings, even the most commonly ...
Marcell M. Bogner, Márton Hegedűs, Péter P. Kalapos, Attila Kunfi, Gábor London   +4 more
wiley   +1 more source

Arene Incorporation and Ring Expansion in the Thermal Decomposition of a Divanadium(III) Complex With Four Bridging Methyl Groups

Chemistry – A European Journal, EarlyView.
Thermolysis of [{VCp*(µ‐CH3)2}2] (Cp* = η5‐C5Me5) in hexane leads to a tetranuclear cube‐type methylidene complex [{VCp*(µ3‐CH2)}4], while in benzenic solvents C6H5R produces the formal insertion of a CH fragment into the six‐membered aromatic ring of a solvent molecule to give trovacene derivatives with η7‐cycloheptatrienyl ligands [VCp*(η7‐C7H6R ...
Adrián Calvo‐Molina, Rodrigo González‐Prieto, Jesús Jover, Adrián Pérez‐Redondo, José Luis Priego, Carlos Yélamos   +5 more
wiley   +1 more source

α-Substituted Benzylic Complexes of Palladium(II) as Precursors of Palladium Hydrides

, 2018
Blanca Martín‐Ruiz, Ignacio Pérez‐Ortega, Ana C. Albéniz   +2 more
openalex   +2 more sources

Ternary Ruthenium Complex Hydrides for Ammonia Synthesis

, 2020
Qianru Wang, Jaysree Pan, Jianping Guo, Heine Anton Hansen, Hua Xie, Ling Jiang, Lei Hua, Haiyang Li, Yeqin Guan, Peikun Wang, Wenbo Gao, Lin Liu, Hunjun Cao, Zhitao Xiong, Tejs Vegge, Ping Chen   +15 more
openalex   +1 more source

Synthesis and Isolation of Bismuth Scorpionate Complexes: Toward Bond Activation via Bismuth‐Ligand Cooperation

Chemistry – A European Journal, EarlyView.
ABSTRACT Over the past twenty years, main group chemistry has significantly expanded its scope to include reactivities once considered the exclusive domain of transition metals. Among the emerging concepts, element‐ligand cooperation has proven to be a powerful strategy for enabling bond activation reactions but remains relatively unexplored for ...
Lennart Hensle, Viktoria H. Gessner
wiley   +1 more source

Mechanistic Insight into NN Cleavage by a Low-Coordinate Iron(II) Hydride Complex

, 2007
A.R. Sadique, Elizabeth A. Gregory, William W. Brennessel, Patrick L. Holland   +3 more
openalex   +2 more sources

Mathematical modeling and multiobjective optimization complex catalyst hydroalumination reaction of olefins with diisobutylaluminium hydride

, 2021
К. Ф. Коледина, I. M. Gubaydullin, С. Н. Коледин   +2 more
openalex   +1 more source

Synthesis of 1‐Alkynylboronates, 1,1‐Diborylalkenes, and 1,1,1‐Triborylalkanes: Challenges and Opportunities

Chemistry – A European Journal, EarlyView.
ABSTRACT In the field of organoboron chemistry, multi(boronate) esters have emerged as crucial intermediates, with various applications in synthetic chemistry, material technology, and life sciences. This mini‐review discusses recent advancement in the synthesis of these versatile compounds, particularly alkynylboronates, 1,1‐diborylalkenes, and 1,1,1 ...
Son Hoai Doan, Vu Nguyen Tran, Thanh Vinh Nguyen   +2 more
wiley   +1 more source