Results 171 to 180 of about 31,033 (331)

Arene Insertion Reactivity of α‑Diimine-Supported Cobalt(I) Hydrides. [PDF]

Organometallics
Moffa KL, Palmer WN, Pecoraro MV, Pappas I, Bezdek MJ, Chirik PJ.   +5 more
europepmc   +1 more source

Anthracene-scaffolded model complexes of [Fe]-hydrogenase (Hmd) for improved functional reactivity and mechanistic investigations of biomimetic H₂ activation and hydride transfer

, 2020
Spencer A. Kerns, 0000-0001-6936-8098
openalex   +1 more source

Metal Nanoparticles on Halloysite Applied in Stereoselective Hydrogenation of Tetrasubstituted Alkenes

Chemistry – A European Journal, EarlyView.
Composite materials based on metal nanoparticles supported on a naturally occurring nanotubular clay, halloysite (HAL), led to the diastereoselective hydrogenation of tetra‐substituted alkenes under relatively smooth conditions, mainly oxazolidinone‐based heterocycles.
Rosa Pich, Gabriel Domínguez, Leo Westrey, Pierre Lavedan, Sonia Mallet‐Ladeira, Jérôme Esvan, Jean‐François Lahitte, Jean‐Christophe Remigy, Daniel Pla, Montserrat Gómez   +9 more
wiley   +1 more source

Mechanistic Insights into Regioselective Arene Insertion Using Bis(phosphine) Cobalt(I) Hydrides to Form 1,3-Cyclohexadienes. [PDF]

Organometallics
Lebowitz MJ, Mendelsohn LN, Zhong H, Pecoraro MV, Shevlin M, Chirik PJ.   +5 more
europepmc   +1 more source

Complex Hydride‐Based Gel Polymer Electrolytes for Rechargeable Ca‐Metal Batteries [PDF]

T. Shinohara, Kazuaki Kisu, Arunkumar Dorai, Kenji Zushida, Hiroshi Yabu, Shigeyuki Takagi, Shin‐ichi Orimo   +6 more
openalex   +1 more source

Unlocking Heterobimetallic Architectures in a Symmetric PNNP Ligand Environment

Chemistry – A European Journal, EarlyView.
A symmetric PNNP ligand enables the modular assembly of heterobimetallic ZnRu and CoRu complexes from a mononuclear Ru(II) precursor. Ligand deprotonation triggers dearomatization and contraction of the metal–metal distance. Combined DFT and QTAIM analyses reveal metallophilic interaction in CoRu but not in ZnRu, highlighting controllable geometric and
Stanislav Melnikov, Menne W. P. Verkooijen, Jop Verduin, Martin Lutz, Daniël L. J. Broere   +4 more
wiley   +1 more source

Stability and hydrogen storage potential of zirconium-based A₂ZrH₆ (A = Na, K) hydrides: a DFT and AIMD investigation. [PDF]

RSC Adv
Kaleem M, Nasir A, Sarfraz Z, Kanwal S, Khan AN, El-Rehim AFA, Zahran HY.   +6 more
europepmc   +1 more source

Alkene Hydrogenation by a Cationic, Nine‐Coordinate Molybdenum(VI) Pentahydride Catalyst

Chemistry – A European Journal, EarlyView.
While late 3d metals dominate efforts to replace precious metals in homogeneous hydrogenation, molybdenum has remained largely ignored. This work reveals that a nine‐coordinate pentahydrido molybdenum complex can hydrogenate a broad range of alkenes efficiently, demonstrating that early‐metal polyhydrides can serve as genuine catalysts rather than mere
Arno Estival, Michel Sigrist, Nicolas Queyriaux, Jorge J. Cabrera‐Trujillo, Nina Durvin, Marie‐Christine Boegli, Laure Vendier, Mary Grellier, Karinne Miqueu, Antoine Simonneau   +9 more
wiley   +1 more source

Lewis Base Complexes of Borane as Hydride Sources and C-B Bond Forming Reactions of the Resulting Electrophilic Boron.

, 2008
Timothy S. DeVries
openalex   +1 more source