Results 181 to 190 of about 31,033 (331)

Iridium Complexes of a Triazole‐Derived Pincer Ligand: Synthesis, Reactivity, and Transfer Dehydrogenation Catalysis

open access: yesChemistry – A European Journal, EarlyView.
Ir pincer complexes bearing a triazole architecture in the pincer backbone and O‐ancillary chelating ligands are presented. These were employed in the catalytic transfer dehydrogenation of alkanes as well as of saturated heterocycles. Reactivity of these complexes with silver salts and Lewis acids produced various cationic iridium complexes.
Jesvita Cardozo   +5 more
wiley   +1 more source

Alkali metal cation effects for rapid C-H activation by iron(0) complexes. [PDF]

open access: yesChem Sci
Hidalgo N   +6 more
europepmc   +1 more source

Iridium‐Catalyzed Linear‐Selective sp3 C−H Alkylation of N‐Methylamides Using Alkenes Enabled by Diphosphite Ligands

open access: yesChemistry – A European Journal, EarlyView.
An iridium‐catalyzed linear‐selective sp3 C─H alkylation of N‐methylamides with alkenes is described. This method tolerates various N‐methylacetamide derivatives and has a broad alkene scope. Mechanistic studies were also conducted. Internal alkenes can also be used through in situ consecutive alkene isomerization.
Haluhi Takahashi, Takanori Shibata
wiley   +1 more source

Copper–Ligand Cooperativity in H 2 Activation Enables the Synthesis of Copper Hydride Complexes

open access: green, 2021
Alicia Aloisi   +6 more
openalex   +2 more sources

A General Strategy for the Synthesis of Jerangolids Enabled by π‐allyl Stille Coupling

open access: yesChemistry – A European Journal, EarlyView.
A general strategy for the synthesis of jerangolids is established, featuring a late‐stage π‐allyl Stille coupling of two advanced, highly customizable building blocks to form the skipped diene core. The approach provides access to all naturally occurring jerangolids, including jerangolid H, whose configuration is confirmed by NMR analysis.
Janick Schug   +2 more
wiley   +1 more source

Amine‐Triggered Azabenz‐Annulation of Cyclic Secondary Amine‐Functionalized Perylene Diimides for Dual‐Mode Sensing

open access: yesChemistry – A European Journal, EarlyView.
Pictet‐Spengler Intermediate of a cyclic secondary amine perylene diimide undergoing amine‐triggered conversion to azabenz‐annulated perylene diimide, inducing a high‐contrast green‐to‐yellow color change along with fluorescence turn‐on, demonstrating intuitive “safe” to “warning” dual‐mode sensing.
Irene E. Park   +2 more
wiley   +1 more source

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