Results 201 to 210 of about 10,236 (282)

Identification of Au-hydrides as key intermediates in the reduction of Au(iii) prodrugs to active Au(i) species under protic conditions. [PDF]

Chem Sci
Ochs J, Metzler-Nolte N.
europepmc   +1 more source

Oxidative Generation and Reactivity of the Cyclopropyl Radical From a Martin Silicate

Chemistry – A European Journal, EarlyView.
A photoredox strategy employing Martin silicates enables the oxidative generation and controlled capture of cyclopropyl radicals, including the naked one, long considered challenging intermediates. The method affords functionalized cyclopropanes through both Giese‐type additions and dual nickel/photoredox C(sp3)−C(sp2) cross‐couplings.
Amal Lakhal, Alexandre Millanvois, Louis Fensterbank, Cyril Ollivier   +3 more
wiley   +1 more source

Si-O Bond Formation Mediated by an Osmium-Polyhydride: Dehydrogenative Silylation of Alcohols and Tandem Hydrosilylation/Dehydrogenative Silylation of Salicylaldehydes. [PDF]

Inorg Chem
Alli IV, Oñate E, Oliván M.
europepmc   +1 more source

Catalyst‐Free Selective Reduction of Nitrogen Dioxide to Nitric Oxide

Chemistry – A European Journal, EarlyView.
Common main group reductants selectively convert nitrogen dioxide to nitric oxide in a catalyst‐free manner. Computational studies suggest divergent reaction pathways depending on the reductant employed. Where boranes and silanes proceed via a two‐electron process, and hydrogen surrogates undergo stepwise one‐electron processes.
Awais W. Seyyad, Agamemnon E. Crumpton, Reece Lister‐Roberts, Meera Mehta   +3 more
wiley   +1 more source

"DIVE" into hydrogen storage materials discovery with AI agents. [PDF]

Chem Sci
Zhang D, Jia X, Tran HB, Jang SH, Zhang L, Sato R, Hashimoto Y, Sato T, Konno K, Orimo SI, Li H.   +10 more
europepmc   +1 more source

Germylium Catalyzed Dehydrofluorination Reactions of Fluorinated Alkanes

Chemistry – A European Journal, EarlyView.
Dehydrofluorination reactions of fluorinated alkanes catalyzed by germylium ions are reported. Computational studies of the mechanism revealed an E2 type mechanism involving a germane as a base to facilitate olefin formation in competition with an SN2 mechanism for hydrodefluorination.
Julie Borel, Morten Lehmann, Martin Kaupp, Thomas Braun   +3 more
wiley   +1 more source

First-principles study of novel Cs₂LuCoH₆ and Cs₂LuZnH₆ double hydride perovskites for hydrogen storage applications. [PDF]

RSC Adv
Almufarij RS, Hayat MS, Khalil RMA, Alghamdi SM, Shokralla EA, Arayro J, Fahmy MA, Siddig MA, Samir A, Ashfaq A.   +9 more
europepmc   +1 more source

Expanding Cyanide‐Bridged Weakly Coordinating Anions Through the Brominated Silver Salt Ag[BCNBBr]

Chemistry – A European Journal, EarlyView.
The brominated weakly coordinating anion [μ‐(CN)(B(C6F4Br)3)2] ([BCNBBr]−), based on two B(C6F4Br)3 units bridged by cyanide, is obtained as its silver salt Ag[BCNBBr] from CH2Cl2. Ag[BCNBBr] enables oxidation and halide abstraction reactions, affording diverse [BCNBBr]− salts with oxidizing and electrophilic cations.
Amina L. Moshtaha, Tim‐Niclas Streit, Joshua Parche, Robin Sievers, Moritz Malischewski   +4 more
wiley   +1 more source

Physically interpretable descriptors drive the materials design of metal hydrides for hydrogen storage. [PDF]

Chem Sci
Jang SH, Zhang D, Tran HB, Jia X, Konno K, Sato R, Orimo SI, Li H.   +7 more
europepmc   +1 more source

Sustainable Hydrogen Production by Glycerol and Monosaccharides Catalytic Acceptorless Dehydrogenation (AD) in Homogeneous Phase

ChemSusChem, Volume 18, Issue 6, March 15, 2025.
Sustainable hydrogen production can be obtained from hydogen‐rich biomass‐derived organic molecules through Acceptorless Dehydrogenation (AD) reactions. Glycerol and sugars are available in large quantities from industry and can be successfully used as substrates in AD protocols, in the presence of tailored, selective, easily tunable and thermally ...
Sylwia Kostera, Luca Gonsalvi
wiley   +1 more source