Chemistry – A European Journal, EarlyView.Homo‐ and heterodinuclear group 4 metallocene complexes of the type [(Cp2M)2(μ‐Me)(μ‐C2R)] (M = Ti, Zr) are active catalysts for the polymerization of ethylene in the presence of aluminium‐free activators. The catalytically active species are proposed to have dinuclear character and depending on the type of activator, unique reactivity was observed ...
Hanan Al Hamwi +8 more
wiley +1 more source
Alkali and Alkaline Earth Metal Hydrides Driven Thermochemical Reduction of CO<sub>2</sub> to CH<sub>3</sub>OH at Ambient Pressure. [PDF]
ACS OmegaMafokoane MA +4 more
europepmc +1 more source
Chemistry – A European Journal, EarlyView.A synthetic methodology has been developed to prepare multifunctional M6P and M6Pn ligands of different valency. The glycopeptides were conjugated to cetuximab and then examined to mediate cellular uptake of fluorescently labeled EGFRvIII. Only cetuximab modified by glycopeptides having 3 or 6 M6P or M6Pn residues demonstrated greater uptake.
Patrycja Lenartowicz +6 more
wiley +1 more source
Synthesis of high-entropy hydride from the cantor alloy (fcc-CoCrFeNiMn) at extreme conditions. [PDF]
Nat CommunGlazyrin K +18 more
europepmc +1 more source
Flipping the Card With Enantiodivergent Organocatalysis
Chemistry – A European Journal, EarlyView.This minireview elaborates on recent organocatalytic strategies for achieving enantiodivergence—the ability to access both product enantiomers using a single chiral catalyst. It highlights how achiral stimuli, such as solvent polarity and chemical additives, along with minimal catalyst modifications, trigger stereochemical inversions in reactions ...
Debora Iapadre +3 more
wiley +1 more source
Influence of B'-site vacancy on hydrogen storage, structural, elastic, thermodynamic and optoelectronic attributes of potassium based double perovskite K<sub>2</sub>LiAlH<sub>6</sub>hydride for green energy applications. [PDF]
Sci RepMurtaza H +7 more
europepmc +1 more source
The Role of Iron‐Hyponitrite Intermediates in Biology and Insights From Synthetic Model Complexes
Chemistry – A European Journal, EarlyView.Despite the difference in active site architecture, NO reduction by different NOR enzymes is expected to be linked by a common intermediate: hyponitrite (N2O22−). However, experimentally, very little is known about the coordination chemistry of iron with hyponitrite and the expected Fe‐hyponitrite intermediates.
Michael O. Lengel, Nicolai Lehnert
wiley +1 more source
Late‐Stage Modification of Halotryptophan‐Containing Peptides Via Negishi Cross‐Coupling
Chemistry – A European Journal, EarlyView.Negishi cross‐coupling provides access to the late‐stage functionalization of bromotryptophan‐containing peptides under comparatively mild conditions and is applicable to a range of peptide substrates in the investigated model systems. The examined alkyl iodides and variation of N‐terminal residues demonstrate the feasibility of the transformation in a
Laura Cerveson +2 more
wiley +1 more source
Hydrogen Embrittlement Behavior of Laser Melting Deposited Ti-6Al-4V Alloy with Different Build Orientations. [PDF]
Materials (Basel)Jiang K +8 more
europepmc +1 more source
Chemistry – A European Journal, EarlyView.Organo‐functionalized molecular molybdenum sulfides were synthesized using bidentate N‐donor ligands and investigated as light‐driven homogeneous hydrogen evolution reaction (HER) catalysts. Trends observed in the HER activity of these catalysts were elucidated by combining photophysical, electrochemical and computational studies.
Moritz Jahn +9 more
wiley +1 more source