Alkali and Alkaline Earth Metal Hydrides Driven Thermochemical Reduction of CO<sub>2</sub> to CH<sub>3</sub>OH at Ambient Pressure. [PDF]
Mafokoane MA +4 more
europepmc +1 more source
Ir pincer complexes bearing a triazole architecture in the pincer backbone and O‐ancillary chelating ligands are presented. These were employed in the catalytic transfer dehydrogenation of alkanes as well as of saturated heterocycles. Reactivity of these complexes with silver salts and Lewis acids produced various cationic iridium complexes.
Jesvita Cardozo +5 more
wiley +1 more source
Synthesis of high-entropy hydride from the cantor alloy (fcc-CoCrFeNiMn) at extreme conditions. [PDF]
Glazyrin K +18 more
europepmc +1 more source
An iridium‐catalyzed linear‐selective sp3 C─H alkylation of N‐methylamides with alkenes is described. This method tolerates various N‐methylacetamide derivatives and has a broad alkene scope. Mechanistic studies were also conducted. Internal alkenes can also be used through in situ consecutive alkene isomerization.
Haluhi Takahashi, Takanori Shibata
wiley +1 more source
Influence of B'-site vacancy on hydrogen storage, structural, elastic, thermodynamic and optoelectronic attributes of potassium based double perovskite K<sub>2</sub>LiAlH<sub>6</sub>hydride for green energy applications. [PDF]
Murtaza H +7 more
europepmc +1 more source
Pictet‐Spengler Intermediate of a cyclic secondary amine perylene diimide undergoing amine‐triggered conversion to azabenz‐annulated perylene diimide, inducing a high‐contrast green‐to‐yellow color change along with fluorescence turn‐on, demonstrating intuitive “safe” to “warning” dual‐mode sensing.
Irene E. Park +2 more
wiley +1 more source
[Ti(py)4I2] as an Entry Point to Titanium(II) Chemistry via Titanium Metal Oxidation
A strategically novel approach based on the oxidation of Ti metal enables access to Ti(II) chemistry. Controlled formation and complexation of Ti diiodide affords the Ti(II) complex [Ti(py)4I2], which serves as a convenient entry point to Ti(II) compounds.
Alexander Sedykh
wiley +1 more source
Identification of Au-hydrides as key intermediates in the reduction of Au(iii) prodrugs to active Au(i) species under protic conditions. [PDF]
Ochs J, Metzler-Nolte N.
europepmc +1 more source
Reduction reactions with complex hydrides [PDF]
Aluminiumhydrid und komplexe Aluminiumhydride haben besondere Aufmerksamkeit für ihre Verwendung als Wasserstoffspeichermaterialien erhalten, sie sind jedoch auch besonders interessant für ihre Verwendung als Reduktionsmittel in der organischen Chemie.
openaire
Experimental methods in chemical engineering: Atomic absorption spectrometry—AAS
Abstract Elements absorb electromagnetic radiation (light) of a specific wavelength in proportion to the number of atoms in its path. As the atoms absorb this light energy, electrons rise from the ground state to an excited state. In atomic absorption spectrometry (AAS), high temperatures produce clouds of atoms from the sample (atomization) and ...
Emily Cintia Tossi de A. Costa +4 more
wiley +1 more source

