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The Formation of Metal Hydrides on the Surface of Spherical Structures and the Numerical Evaluation of the Hydrogenation Process. [PDF]
Khalil Z, Kavaliauskas Ž.
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Multidimensional pH-Temperature Mapping of SABRE-SHEATH <sup>13</sup>C Hyperpolarization of [1-<sup>13</sup>C]Pyruvate. [PDF]
Adelabu I +18 more
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Investigation of the La-Al-H and La-Si-H Systems at High Pressures. [PDF]
Beyer DC +11 more
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Variation of Nucleophilicity N<sub>HnA</sub> of Atoms A in Hydrides H<sub>n</sub>A with the Group and Row of A in the Periodic Table. [PDF]
Alkorta I, Legon A.
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A Theoretical Investigation on the Hydrogen Bond Based on the GLED Method of Bonding Analysis. [PDF]
Borocci S +3 more
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Chemical Reviews, 2016
Nickel hydride complexes, defined herein as any molecules bearing a nickel hydrogen bond, are crucial intermediates in numerous nickel-catalyzed reactions. Some of them are also synthetic models of nickel-containing enzymes such as [NiFe]-hydrogenase. The overall objective of this review is to provide a comprehensive overview of this specific type of ...
Nathan A, Eberhardt, Hairong, Guan
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Nickel hydride complexes, defined herein as any molecules bearing a nickel hydrogen bond, are crucial intermediates in numerous nickel-catalyzed reactions. Some of them are also synthetic models of nickel-containing enzymes such as [NiFe]-hydrogenase. The overall objective of this review is to provide a comprehensive overview of this specific type of ...
Nathan A, Eberhardt, Hairong, Guan
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Catalyzed Complex Metal Hydrides
MRS Bulletin, 2002AbstractComplex hydrides are mixed ionic–covalent compounds that can serve as reversible H2storage media only when they are catalyzed by a transition metal such as Ti. As the prime example, the phenomenology of Ti-catalyzed sodium alanate (NaAlH4) is reviewed from a historical perspective.
Bogdanović, B., Sandrock, G.
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Trinuclear rhodium hydride complexes
Dalton Transactions, 2011Three novel trinuclear rhodium hydride complexes of the type {[Rh(PP*)H](3)(μ(2)-H)(3)(μ(3)-H)}[BF(4)](2) containing diphosphines Tangphos, t-Bu-BisP* and Me-DuPHOS have been synthesised. The new compounds are very stable. Their structures have been characterized by X-ray analysis in the solid state and by NMR-spectroscopic investigations in solution.
Christian, Fischer +4 more
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Scripta Materialia, 2007
NaAlH4 is amongst the most advanced and intensely investigated hydrogen storage materials today. It reaches a storage capacity of more than 5 wt.% at around 100 °C. By suitable doping with catalysts, the re- and de-hydrogenation kinetics can be dramatically improved so that re-hydrogenation times on the order of minutes can be achieved.
Bogdanović, B. +3 more
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NaAlH4 is amongst the most advanced and intensely investigated hydrogen storage materials today. It reaches a storage capacity of more than 5 wt.% at around 100 °C. By suitable doping with catalysts, the re- and de-hydrogenation kinetics can be dramatically improved so that re-hydrogenation times on the order of minutes can be achieved.
Bogdanović, B. +3 more
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Light metal hydrides and complex hydrides for hydrogen storage
Chem. Commun., 2004AbstractFor Abstract see ChemInform Abstract in Full Text.
Schüth, F. +2 more
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