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Complex Hydrides for Hydrogen Storage
ChemInform, 2007AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.
Shin-Ichi, Orimo +4 more
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Journal of Materials Chemistry A, 2022
Water molecules are exchanged in the crystal structure, which imparts a high divalent conductivity to hydrated complex hydrides. MB12H12·12H2O (M = Zn or Mg) exhibits exceptional conductivities higher than those of less-hydrated complex hydrides.
K. Kisu +9 more
semanticscholar +1 more source
Water molecules are exchanged in the crystal structure, which imparts a high divalent conductivity to hydrated complex hydrides. MB12H12·12H2O (M = Zn or Mg) exhibits exceptional conductivities higher than those of less-hydrated complex hydrides.
K. Kisu +9 more
semanticscholar +1 more source
Complex hydrides for CO2 reduction
MRS bulletin, 2022Fossil fuels consumption is not expected to decrease significantly in the next decade, driving the atmospheric carbon dioxide concentration upward. Tremendous efforts have been made in the field of carbon capture with the development of porous material ...
Loris Lombardo +3 more
semanticscholar +1 more source
Chemical Reviews, 2016
Nickel hydride complexes, defined herein as any molecules bearing a nickel hydrogen bond, are crucial intermediates in numerous nickel-catalyzed reactions. Some of them are also synthetic models of nickel-containing enzymes such as [NiFe]-hydrogenase. The overall objective of this review is to provide a comprehensive overview of this specific type of ...
Nathan A, Eberhardt, Hairong, Guan
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Nickel hydride complexes, defined herein as any molecules bearing a nickel hydrogen bond, are crucial intermediates in numerous nickel-catalyzed reactions. Some of them are also synthetic models of nickel-containing enzymes such as [NiFe]-hydrogenase. The overall objective of this review is to provide a comprehensive overview of this specific type of ...
Nathan A, Eberhardt, Hairong, Guan
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Complex Hydrides for Energy Storage, Conversion, and Utilization
Advances in Materials, 2019Functional materials are the key enabling factor in the development of clean energy technologies. Materials of particular interest, which are reviewed herein, are a class of hydrogenous compound having the general formula of M(XHn)m, where M is usually a
Teng He, Hujun Cao, Ping Chen
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Catalyzed Complex Metal Hydrides
MRS Bulletin, 2002AbstractComplex hydrides are mixed ionic–covalent compounds that can serve as reversible H2storage media only when they are catalyzed by a transition metal such as Ti. As the prime example, the phenomenology of Ti-catalyzed sodium alanate (NaAlH4) is reviewed from a historical perspective.
Bogdanović, B., Sandrock, G.
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, 2020
Supported aluminum-based complex hydrides (alanates) were investigated in view of their interaction at the interface.
Youngdon Ko +5 more
semanticscholar +1 more source
Supported aluminum-based complex hydrides (alanates) were investigated in view of their interaction at the interface.
Youngdon Ko +5 more
semanticscholar +1 more source
Trinuclear rhodium hydride complexes
Dalton Transactions, 2011Three novel trinuclear rhodium hydride complexes of the type {[Rh(PP*)H](3)(μ(2)-H)(3)(μ(3)-H)}[BF(4)](2) containing diphosphines Tangphos, t-Bu-BisP* and Me-DuPHOS have been synthesised. The new compounds are very stable. Their structures have been characterized by X-ray analysis in the solid state and by NMR-spectroscopic investigations in solution.
Christian, Fischer +4 more
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Scripta Materialia, 2007
NaAlH4 is amongst the most advanced and intensely investigated hydrogen storage materials today. It reaches a storage capacity of more than 5 wt.% at around 100 °C. By suitable doping with catalysts, the re- and de-hydrogenation kinetics can be dramatically improved so that re-hydrogenation times on the order of minutes can be achieved.
Bogdanović, B. +3 more
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NaAlH4 is amongst the most advanced and intensely investigated hydrogen storage materials today. It reaches a storage capacity of more than 5 wt.% at around 100 °C. By suitable doping with catalysts, the re- and de-hydrogenation kinetics can be dramatically improved so that re-hydrogenation times on the order of minutes can be achieved.
Bogdanović, B. +3 more
openaire +2 more sources
Light metal hydrides and complex hydrides for hydrogen storage
Chem. Commun., 2004AbstractFor Abstract see ChemInform Abstract in Full Text.
Schüth, F. +2 more
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