Results 11 to 20 of about 481,621 (347)
Triggering Redox Activity in a Thiophene Compound: Radical Stabilization and Coordination Chemistry [PDF]
The synthesis, metalation, and redox properties of an acyclic bis(iminothienyl)methene L− are presented. This π-conjugated anion displays pronounced redox activity, undergoing facile one-electron oxidation to the acyclic, metal-free, neutral radical L ...
Massimiliano Curcio +4 more
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Photodynamic therapy (PDT) has attracted much attention in the field of anticancer treatment. However, PDT has to face challenges, such as aggregation caused by quenching of reactive oxygen species (ROS), and short 1O2 lifetime, which lead to ...
Jiahe Zhou +6 more
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All-inorganic nanocrystals are of great importance for a variety of electronic applications. Here, the authors use metal salts to remove organic ligands to obtain passivated nanocrystals with improved fluorescence yield for direct optical patterning.
Pengwei Xiao +9 more
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The coordination chemistry of saturated molecules [PDF]
Our understanding of bonding in transition metal complexes, as well as our ability to use that understanding in the synthesis and application of new species, has evolved over the last 100 years; and in some sense this special feature on the coordination ...
Bercaw, John E., Labinger, Jay A.
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A dual-labeling probe to track functional mitochondria–lysosome interactions in live cells
Dynamic labeling and tracking of organelle–organelle contacts is essential to understand the formation and function of these interactions. Here the authors present a small molecule probe, Coupa, that labels mitochondria and lysosomes with blue and red ...
Qixin Chen +13 more
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Komplexchemie perhalogenierter Cyclopentadiene und Alkine, VII [PDF]
Coordination Chemistry of Perhalogenated Cyclopentadienes and Alkynes, VII1). - Synthesis of Several Tetrachlorometalloles of Cobalt, Rhodium, and Iridium; Structure of a Iridacyclopentadiene Derivative The reaction of dichloroethyne with CpCo(PPh3)2 ...
Clarke +15 more
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Coordination chemistry of perhalogenated cyclopentadienes and alkynes. 8. Pentakis(dimethylsilyl)cymantrene [PDF]
Starting from [q5-C5Br5]M n(CO),, the first r-complex of a cyclopentadienyl ligand with five silyl substituents, [q 5-C5(SiMe2H)5M] n(CO),, was prepared by a series of halogen-lithium exchange reactions, followed by silylation with SiMe2HCI.
Hofmann, Julian, Sünkel, Karlheinz
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Coordination chemistry of amide-functionalised tetraazamacrocycles: structural, relaxometric and cytotoxicity studies [PDF]
Three different tetraazamacrocyclic ligands containing four amide substituents that feature groups (namely allyl, styryl and propargyl groups) suitable for polymerisation have been synthesised.
Aime +54 more
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Dialkyl biaryl phosphines find wide application in catalysis as ligands. Here, the authors report a rhodium-catalysed hydroarylation of alkenes and alkynes with tertiary phosphines through P(III)-chelation assisted C-H activation affording a library of ...
Dingyi Wang +6 more
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Coordination Chemistry in Zeolites
Zeolites are relatively rigid inorganic matrices with cavities and channels of molecular dimensions and of different sizes and shapes. Transition metal ion (TMI) complexes in molecular sieves have three main characteristics: (1) the complexes have strongly reduced mobility with respect to their solution mobility and deactivating aggregations may be ...
Weckhuysen, B.M. +5 more
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