Copper catalysis in organic synthesis [PDF]
Sherry R. Chemler
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Chiral Copper Catalysis in Enantioselective Domino Reactions [PDF]
This review updates the field of enantioselective copper-catalysed domino reactions promoted by chiral green copper catalysts, covering the literature since 2017.
Hélène Pellissier
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Copper catalysis with redox-active ligands [PDF]
Copper catalysis finds applications in various synthetic fields by utilizing the ability of copper to sustain mono- and bielectronic elementary steps. Further to the development of well-defined copper complexes with classical ligands such as phosphines ...
Agnideep Das +3 more
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Synergistic photoredox and copper catalysis by diode-like coordination polymer with twisted and polar copper–dye conjugation [PDF]
Synergistic photoredox–copper catalysis is limited by fluorescence quenching of Cu(II) ions to photoreductive dyes in solution. Here, the authors compromise photoreduction and Cu(II) catalysis by diode-like coordination polymer with twisted Cu(II)–dye ...
Yusheng Shi +5 more
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Recent advances in electrochemical copper catalysis for modern organic synthesis [PDF]
In recent decades, organic electrosynthesis has emerged as a practical, sustainable, and efficient approach that facilitates valuable transformations in synthetic chemistry.
Yemin Kim, Won Jun Jang
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High‐Valent Copper Catalysis Enables Regioselective Fluoroarylation of Gem‐Difluorinated Cyclopropanes [PDF]
Transition‐metal (TM) catalyzed reaction of gem‐difluorinated cyclopropanes (gem‐DFCPs) has drawn much attention recently. The reaction generally occurs via the activation of the distal C─C bond in gem‐DFCPs by a low‐valent TM through oxidative addition,
Xiuli Wu, Xiangyu Song, Ying Xia
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Aryl iodane-induced cascade arylation–1,2-silyl shift–heterocyclization of propargylsilanes under copper catalysis [PDF]
A novel copper-catalyzed arylation strategy for propargylsilanes utilizing diaryl-λ3-iodanes has been developed, enabling a cascade sequence involving 1,2-silyl migration and heterocyclization. The β-silicon effect facilitates the formation of stabilized
Rasma Kroņkalne +4 more
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Copper catalysis at operando conditions—bridging the gap between single nanoparticle probing and catalyst-bed-averaging [PDF]
Characterizing individual catalyst nanoparticles at operando conditions is a cornerstone of catalysis research. Here the authors utilize plasmonic optical nanoimaging in a nanofluidic reactor to map the impact of reactor geometry on single Cu particle ...
David Albinsson +6 more
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Desymmetrization of meso-bisphosphates using copper catalysis and alkylzirconocene nucleophiles [PDF]
Copper-catalyzed allylic desymmetrizations are, so far, limited to carbocyclic products with two tertiary stereocenters. Here, the authors report a highly enantioselective Cu-catalyzed desymmetrization of meso carbo- and hetero-cyclic bisphosphates to ...
Reece Jacques +2 more
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Copper Catalysis-Based Amperometric Microsensors for Carbon Dioxide Monitoring [PDF]
Mengwen Guo +3 more
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