Results 21 to 30 of about 39,473 (242)
Nature Communications, 2021 Vicinal dicarbofunctionalization (DCF) reactions of alkenes have been extensively explored in ionic chemistry but the enantioselective radical mediated version of DCF remains largely unexplored.
Peng-Zi Wang +5 more
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Desymmetrization of 1,4‐Cyclohexadienyltriisopropoxysilane Using Copper Catalysis. [PDF]
ChemInform, 2007 AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.
Rui, Umeda, Armido, Studer
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Asymmetric cyanoesterification of vinylarenes by electrochemical copper catalysis. [PDF]
Nat CommunThe heterodifunctionalization of alkenes is an efficient and straightforward method for the preparation of highly functionalized molecules. However, enantioselective introduction of two different carbon-based functional groups in a single step using readily accessible and inexpensive starting materials presents a significant challenge.
Zhou K, Fu N.
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Beilstein Journal of Organic Chemistry, 2021 Electrocatalytic dehydrogenative C(sp3)–H/C(sp)–H cross-coupling of tetrahydroisoquinolines with terminal alkynes has been achieved in a continuous-flow microreactor through 2,2,6,6-tetramethylpiperidine 1-oxyl (TEMPO)/copper relay catalysis.
Bin Guo, Hai-Chao Xu
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Copper(I)-catalyzed asymmetric alkylation of α-imino-esters
Nature Communications, 2023 Asymmetric alkylation of enolates is one of the most direct and important reactions to prepare α-chiral carbonyl compounds. Except for the classical methods that rely on the use of chiral auxiliaries, asymmetric catalysis emerged as a powerful tool ...
Zong-Ci Liu +3 more
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Copper's Contribution to Amination Catalysis [PDF]
Science, 2013 Copper complexes catalyze a remarkably broad range of organic reactions that form carbon-nitrogen bonds.
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Nature Communications, 2022 Copper hydrides have been studied for their exciting structural chemistry and applications in hydrogenation catalysis. Here, the authors uncover the role of the amidinate ligand in yielding two closely related copper hydride clusters with quite different
Chun-Yu Liu +5 more
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Recent advances in copper-catalyzed C–H bond amidation
Beilstein Journal of Organic Chemistry, 2015 Copper catalysis has been known as a powerful tool for its ubiquitous application in organic synthesis. One of the fundamental utilities of copper catalysis is in the C–N bond formation by using carbon sources and nitrogen functional groups such as ...
Jie-Ping Wan, Yanfeng Jing
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Trifluoromethylation of Allylsilanes under Copper Catalysis
Chemistry – A European Journal, 2012 The trifluoromethylation reactions are performed with Togni reagent (II) to give branched allylic trifluoromethylated products.
Mizuta, S +6 more
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Identification of a tyrosine switch in copper-haem nitrite reductases
IUCrJ, 2018 There are few cases where tyrosine has been shown to be involved in catalysis or the control of catalysis despite its ability to carry out chemistry at much higher potentials (1 V versus NHE). Here, it is shown that a tyrosine that blocks the hydrophobic
Jianshu Dong +4 more
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