Results 111 to 120 of about 132,024 (337)

Interfacing with silica boosts the catalysis of copper

open access: yesNature Communications, 2018
Metal-support interaction plays an important role in heterogeneous catalysis, but silica has been rarely reported as an effective support to create active metal-support interfaces for promoting catalytic reactions. Here, the authors discover that Cu/SiO2
Chaofa Xu   +8 more
doaj   +1 more source

Density-functional study of Cu atoms, monolayers, and coadsorbates on polar ZnO surfaces

open access: yes, 2003
The structure and electronic properties of single Cu atoms, copper monolayers and thin copper films on the polar oxygen and zinc terminated surfaces of ZnO are studied using periodic density-functional calculations.
B. Meyer   +7 more
core   +1 more source

Photoconductivity‐Driven Quantum Efficiency Gain in Inorganic Ruddlesden‐Popper Layered Cs2PbBr2I2 Perovskite Photodetector for Visible Light Detection

open access: yesAdvanced Functional Materials, EarlyView.
Rational halogen mixing strategy was employed to shift the bandgap of Cs2PbBr2I2 from ultraviolet to visible region, enabling first realization of a visible‐light photodetector with this 2D layered Ruddlesden‐Popper perovskite material. Under illumination, light‐induced internal field forms and drives trap‐mediated persistent photoconductivity ...
Md Fahim Al Fattah   +11 more
wiley   +1 more source

SOD activity of immobilized enzyme mimicking complexes [PDF]

open access: yes, 2003
A binuclear, imidazolato-bridged, possible superoxide dismutase-mimicking complex (Cu(II)-diethylenetriamino-μ-imidazolato-Zn(II)-tris-aminoethylamine-triperchlorate) was prepared and immobilized on silica gel or among the layers of montmorillonite.
Hernádi, Klára   +4 more
core  

Tuning the Selectivity of the CO2 Reduction Reaction by Means of Synergistic Interactions in the Cu, Ag, Ce System

open access: yesAdvanced Functional Materials, EarlyView.
Multi‐metal Cu─Ce─Ag nanoparticles harness synergistic interactions to drive efficient electrochemical CO2 reduction reaction toward C2+ products at high current densities. Ag enhances CO production, Ce modulates Cu oxidation states, and together they boost *CO coverage and local pH to enhance C─C coupling, enabling record C2+ yields with suppressed ...
Nini Zhang   +9 more
wiley   +1 more source

Light-driven radical copper-catalyzed allylic amination via allylic copper intermediates

open access: yesNature Communications
The synthesis of allylic amines through an outer-sphere nucleophilic substitution mechanism involving electrophilic allyl copper(III) complexes with soft amines represents an uncharted territory in catalysis.
Hang Luo   +9 more
doaj   +1 more source

Intrabandgap States Engineering in Functionalized Nanodiamond to Generate Solvated Electrons for Photocatalysis Under Solar Illumination

open access: yesAdvanced Functional Materials, EarlyView.
The negative electron affinity of diamond allows to emit highly reductive electrons. By introducing intra‐bandgap states and an optimized electron transfer mechanism by surface functionalization with Ru(bpy)3, the formation of solvated electrons is achieved upon solar irradiation.
Benjamin Kiendl   +20 more
wiley   +1 more source

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