Results 231 to 240 of about 1,041,818 (287)
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(−)-Sparteine copper(II) diacetate
Acta Crystallographica Section C Crystal Structure Communications, 2000The chiral nitrogen-chelating alkaloid (−)-sparteine acts as a bidentate ligand, reacting with copper(II) acetate in ethanol to form the title complex, [Cu(CH3COO)2(C15H26N2)], with the two acetate groups occupying the remaining coordination sites in a monodentate fashion to produce a distorted four-coordinate tetrahedral structure.
, Lee, , Chung, , Kwon, , Choi
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Double Hydrated Cobalt(II) Copper(II) and Nickel(II) Copper(II) Ammine Diphosphates
Russian Journal of Applied Chemistry, 2005Synthesis of amorphous and crystalline double hydrated cobalt copper and nickel copper ammine diphosphates with a coordination structure is described.
L. V. Voitenko +2 more
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Homobinuclear Complexes of Copper(II) with Copper(II) Thiocarbohydrazones
Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 1986Abstract Copper(II) binuclear complexes of copper(II) thiocarbohydrazones were prepared by reacting copper(II) acetate with copper(II) thiocarbohydrazones in ethanol. All the complexes are bright green in colour and appear to be non-electrolytes in DMF. Elemental analyses conform to the 1:1 stoichiometry of the type CuL.Cu(OAc)2.
Basavantappa M. Badiger +3 more
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Histidine-Copper (II) Complexes
Nature, 1959STABILITY constants are known for copper complexes of most of the naturally occurring α-amino-acids. However, although it is of considerable biochemical interest, the copper–histidine system has not been interpreted in detail. The system is anomalous, probably because, although the metal can co-ordinate to the amino, imidazole or carboxyl groups in ...
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Polyhedron, 2003
Abstract The strategy of “complex as ligand” allowed us to synthesize three new μ-oxalato-bridged heterotrinuclear complexes identified as [Cu2Cr(ox)3(Mephen)2]ClO4 (1), [Cu2Fe(ox)3(Mephen)2]ClO4 (2) and [Cu2Fe(ox)3(Me2bpy)2]ClO4 (3), where ox represents the oxalato dianions; Mephen and Me2bpy stand for 5-methyl-1,10-phenanthroline and 4,4′-dimethyl ...
Yan-Tuan Li, Cui-Wei Yan, Hua-Shi Guan
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Abstract The strategy of “complex as ligand” allowed us to synthesize three new μ-oxalato-bridged heterotrinuclear complexes identified as [Cu2Cr(ox)3(Mephen)2]ClO4 (1), [Cu2Fe(ox)3(Mephen)2]ClO4 (2) and [Cu2Fe(ox)3(Me2bpy)2]ClO4 (3), where ox represents the oxalato dianions; Mephen and Me2bpy stand for 5-methyl-1,10-phenanthroline and 4,4′-dimethyl ...
Yan-Tuan Li, Cui-Wei Yan, Hua-Shi Guan
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Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 2005
X-band electron spin resonance (ESR) and UV-vis spectra of a homobinuclear [(Bipy)2Cu-E-Im-Cu(Bipy)2](BF4)3 and a heterobinuclear [(Bipy)2Cu-E-Im-Zn(Bipy)2](BF4)3 complexes, E-Im=2-ethylimidazolate ion have been described as possible models for superoxide dismutase (SOD).
R N, Patel +4 more
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X-band electron spin resonance (ESR) and UV-vis spectra of a homobinuclear [(Bipy)2Cu-E-Im-Cu(Bipy)2](BF4)3 and a heterobinuclear [(Bipy)2Cu-E-Im-Zn(Bipy)2](BF4)3 complexes, E-Im=2-ethylimidazolate ion have been described as possible models for superoxide dismutase (SOD).
R N, Patel +4 more
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Transition Metal Chemistry, 2000
Novel complexing processes in the CuII–8-mercaptoquinoline, CuII–5,8-dimercaptoquinoline and CuII–5-thiomethyl-8-mercaptoquinoline systems proceeding in the copper(II)hexacyanoferrate(II) gelatin-immobilized matrix in contact with aqueous solutions of the ligands indicated, have been studied.
Oleg V. Mikhailov +3 more
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Novel complexing processes in the CuII–8-mercaptoquinoline, CuII–5,8-dimercaptoquinoline and CuII–5-thiomethyl-8-mercaptoquinoline systems proceeding in the copper(II)hexacyanoferrate(II) gelatin-immobilized matrix in contact with aqueous solutions of the ligands indicated, have been studied.
Oleg V. Mikhailov +3 more
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Crystallography Reports, 2009
Compounds dinitrato(2-formylpyridinesemicarbazone)copper (I), dichloro(2-formylpyridinesemicarbazone)copper hemihydrate (II), and bis(2-formylpyridine semicarbazone)copper(2+) perchlorate hydrate (III) are synthesized and their crystal structures are determined.
Chumakov Y +7 more
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Compounds dinitrato(2-formylpyridinesemicarbazone)copper (I), dichloro(2-formylpyridinesemicarbazone)copper hemihydrate (II), and bis(2-formylpyridine semicarbazone)copper(2+) perchlorate hydrate (III) are synthesized and their crystal structures are determined.
Chumakov Y +7 more
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Copper(II) Chloride-Copper(II) Oxide
2001(CuCl2) [7447-39-4] Cl2Cu (MW 134.45) InChI = 1S/2ClH.Cu/h2*1H;/q;;+2/p-2 InChIKey = ORTQZVOHEJQUHG-UHFFFAOYSA-L (CuO) [1317-38-0] CuO (MW 79.54) InChI = 1S/Cu.O InChIKey = QPLDLSVMHZLSFG-UHFFFAOYSA-N (carbonyl deprotection reagent; allows transformation of thioacetals, α-heterosubstituted sulfides, and selenoacetals to ...
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Copper(II) Hexafluoroantimonate
2005[25954-61-4] Cu(SbF6)2 (MW 535.05) InChI = 1S/Cu.12FH.2Sb/h;12*1H;;/q+2;;;;;;;;;;;;;2*+5/p-12 InChIKey = QROFREBHJJWTIN-UHFFFAOYSA-B (reagent used as Lewis acid catalyst coordinating with chiral ligand for enantioselective Diels-Alder reactions) Physical Data: white hygroscopic solid; thermally stable up to 210 °C.
Shuh-Kuen Chang, Peter Selvaraj
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