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Zur Struktur rhodiumhaltiger Corrinoide
Liebigs Annalen der Chemie, 1980AbstractDurch Umsetzung von Hydrogenobyrinsäure‐a,c‐diamid (1) mit [Rh(CO)2Cl]2 in Eisessig/Ethanol (1:1; Vol.: Vol.) erhält man als Hauptprodukt Rhodibyrinsäure‐a,c‐diamid 2. Die Identität von 2 wird durch Röntgenstrukturanalyse bestätigt. Veresterung von 2 mit Methanol/Schwefelsäure führt neben Rhodibyrinsäure‐pentamethylester‐a,c‐diamid 3a zu den ...
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Current Microbiology, 1980Corrinoids in several diverse species of methanogens were quantified by a bioassay utilizingEscherichia coli 113-3, a corrinoid auxotroph. All five species examined contained >0.65 nmol corrinoid/mg dry cells when grown on H2/CO2 as carbon and energy source.
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