Results 61 to 70 of about 2,622 (224)

Asymmetric Diphosphane Dioxides With A–π–A–π’–D Scaffolds for High‐Purity Deep‐Blue Luminescence

open access: yesChemistry – A European Journal, EarlyView.
Diphosphane dioxide‐based luminophores with donor–π–acceptor– π’–acceptor scaffold enable efficient deep‐blue emission from tunable charge‐transfer states affording high photoluminescence up to 95%. OLEDs reach EQE 4.9%, aided by triplet–triplet annihilation, highlighting a practical route to high‐performance blue emitters.
Eetu Hakkarainen   +10 more
wiley   +1 more source

Azidophosphonamido Rhodium(I) and Iridium(I) Complexes: Synthesis, Properties, and Linkage Isomerism

open access: yesChemistry – A European Journal, EarlyView.
A family of azidophosphonamido ligands and their corresponding rhodium(I) and iridium(I) complexes were synthesized. The rich reaction chemistry of these species revealed unusual linkage isomerization processes and bonding motifs. M = Rh, Ir; Mes = 2,4,6‐Me3C6H2. ABSTRACT A series of azidophosphonamido rhodium(I) and iridium(I) complexes ([iPr2P(N3R)NR]
Emily L. Trew   +3 more
wiley   +1 more source

Fatigue endurance design of plates with two semicircular edge notches and one quarter-elliptical corner crack or through-the-thickness crack

open access: yes, 2019
This paper presents an investigation on the failure of plates with double-edge notches and fatigue damage. The main aim is to develop a computational model for estimating the behaviour of a quarter-elliptical corner crack or a through-the-thickness crack
Boljanovic S.   +3 more
core   +1 more source

Exploring Calixarene‐Based Pseudorotaxane Architectures: Threading Ammonium Axles With an Exo‐Rim π‐Functionalized Calix[6]Arene Macrocycle

open access: yesChemistry – A European Journal, EarlyView.
This research presents a novel 1,4‐π‐functionalized calix[6]arene with enhanced interactions with dialkylammonium axles. We investigate threading behavior in CDCl3, highlighting how exo‐rim π‐functionalization affects binding affinity and stereoselectivity.
Veronica Iuliano   +7 more
wiley   +1 more source

Efficient Length Doubling From Tweakable Block Ciphers

open access: yesIACR Transactions on Symmetric Cryptology, 2017
We present a length doubler, LDT, that turns an n-bit tweakable block cipher into an efficient and secure cipher that can encrypt any bit string of length [n..2n − 1].
Yu Long Chen   +3 more
doaj   +1 more source

Metal‐Ion Regulated Light‐Free Z→E Isomerization of Azobenzene Glycomacrocycle

open access: yesChemistry – A European Journal, EarlyView.
Metal ion‐catalyzed Z→E isomerization of photoswitchable azobenzene glycomacrocycle: A new azobenzene‐based glycomacrocycle is capable of forming a 1:1 complex with divalent metal ions in both E‐ and Z‐isomers. The complexes undergo light‐free Z→E isomerization in a timescale spanning from seconds to weeks.
Yang Zhou   +4 more
wiley   +1 more source

Privacy-preserving logistic regression training

open access: yesBMC Medical Genomics, 2018
Background Logistic regression is a popular technique used in machine learning to construct classification models. Since the construction of such models is based on computing with large datasets, it is an appealing idea to outsource this computation to a
Charlotte Bonte, Frederik Vercauteren
doaj   +1 more source

A Cytosine‑Bulged (3+1) Hybrid G‑Quadruplex Formed by the Chicken DNA Replication Origin

open access: yesChemistry – A European Journal, EarlyView.
The first high‐resolution structure of an OGRE‐derived G‐quadruplex from the chicken β‐globin replication origin reveals an intramolecular three‐layer (3+1) hybrid fold with a cytosine bulge and an unprecedented 5'‐outer‐quartet anti guanine, creating a distinctive surface for molecular recognition.
Yingying You   +13 more
wiley   +1 more source

Uniform Sharing in Multiple Stages: NullFresh for Arbitrary Functions

open access: yesTransactions on Cryptographic Hardware and Embedded Systems
In the field of hardware masking, threshold implementations are a wellknown technique that provides glitch-resistant power analysis security. While they guarantee probing security, finding a uniform sharing without additional randomness is difficult ...
Artemii Ovchinnikov   +2 more
doaj   +1 more source

Coordination Chemistry of Boron Subphthalocyanine With BINOL Derivatives: Unexpected Oxidation to Oxa[4]Helicene and Properties of the Resulting Axially Coordinated Complexes Containing Oxa[4]Helicene and/or BINOL Derivatives

open access: yesChemistry – A European Journal, EarlyView.
Treatment of BINOL with a boron subphthalocyanine derivative resulted in the formation of a complex coordinated to an oxa[4]helicene derivative, which is generated via a ring‐closure reaction of BINOL. In contrast, treatment of the monomethyl ether of 1,1′‐bi‐2‐naphthol (BINOL) afforded the expected axially coordinated complex.
Shafikul Islam   +5 more
wiley   +1 more source

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