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Thermodynamic coupling in chemical reactions
Journal of Theoretical Biology, 1975The significance of thermodynamic coupling in chemical reactions—which recently has been questioned on thermodynamic grounds—is examined from the point of view of kinetics. It is shown that considerations of stoichiometry lead to a meaningful definition of velocity for elementary and certain elementary-complex reactions, whereas the non-equilibrium ...
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Electrochemical Decarboxylation Coupling Reactions
Chemistry – A European JournalAbstractCarboxylic acids are attractive synthetic feedstocks with stable, non‐toxic, and inexpensive properties that can be easily obtained from natural sources or through synthesis. Carboxylic acids have long been considered environmentally friendly coupling agents in various organic transformations.
Jiaxiu Liu +5 more
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Decarboxylative Coupling Reactions
Israel Journal of Chemistry, 2010AbstractDecarboxylative couplings are chemical transformations in which carboxylic acids extrude CO2 and form new bonds in the place of the former carboxylate group. In recent years, a large number of such reactions with considerable synthetic potential has been developed. This article reviews the rapidly emerging area of decarboxylative couplings.
Lukas J. Goossen +2 more
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A triple search for coupling reactions
Science, 2017Chemistry Coupling reactions are, in principle, good candidates for high-throughput discovery: Simply mix a diverse set of reagents and then look for products that combine two or three of their masses.
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Negishi cross-coupling reaction
2002The Negishi cross-coupling reaction is the nickel- or palladium-catalyzed coupling of organozinc compounds with various halides or triflates (aryl, alkenyl, alkynyl, and acyl).
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COUPLED REACTIONS IN BIOLOGICAL SYSTEMS
Science, 1933H F, Schott, H, Borsook
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1996
Abstract Palladium- and nickel-catalyzed coupling reactions have become a powerful method for the functionalization of alkenes and arenes. There is a broad variety of different reactions to choose from, which in many cases can be used to reach the same synthetic end-point. Moreover, in recent years many different procedures for each type
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Abstract Palladium- and nickel-catalyzed coupling reactions have become a powerful method for the functionalization of alkenes and arenes. There is a broad variety of different reactions to choose from, which in many cases can be used to reach the same synthetic end-point. Moreover, in recent years many different procedures for each type
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