Results 91 to 100 of about 4,073,255 (239)
Alkenol−Alkyne Cross Metathesis
, 2016 Allyl alcohols and their homologues were used in the enyne cross metathesis to prepare hydroxy-functionalized dienes. An isomerization was found to occur under prolonged heating, and a method for conversion to (E)-diene product is also ...
Steven T. Diver (1667287) +2 more
core +1 more source
Thiolate Salt Mediated Dynamic Silyl Ether Exchanges for Polymer Network Design and Deconstruction
Macromolecular Rapid Communications, EarlyView.This work introduces thiolate salts as mediators for dynamic silyl ether exchange. This platform enables the synthesis of reprocessable covalent adaptable polymer networks (CANs) and allows for sterically controlled, and tunable deconstruction of silyl ether‐containing thermosets.
Pierce T. Bombard +9 more
wiley +1 more source
Beilstein Journal of Organic Chemistry, 2020 This account surveys the current progress on the application of intra- and intermolecular enyne metathesis as main key steps in the synthesis of challenging structural motifs and stereochemistries found in bioactive compounds.
Valerian Dragutan +3 more
doaj +1 more source
Macromolecular Rapid Communications, EarlyView.Poly(vinylpyrrolidone) creates a quasi‐stable dispersion copolymerization system that enables direct comparison of the dispersed and precipitated polymer fractions. Structural analysis shows that fractionation correlates more strongly with sulfur rank than with molecular weight, revealing how the number of consecutive sulfur atoms in the polysulfide ...
Takumi Hashimoto +9 more
wiley +1 more source
Heterogeneous catalysts for olefln cross-metathesis
, 2008 Olefin metathesis has been widely used in the fields of petrochemical industry and organic synthesis. It can be classified as ring-opening metathesis, ring-opening metathesis polymerization, ring-closing metathesis and cross-metathesis, etc.
Li Xiujie +3 more
core
Mass Spectrometry Reviews, EarlyView.ABSTRACT The use of MALDI mass spectrometry for the analysis of carbohydrates and glycoconjugates is a well‐established technique and this comprehensive review is the twelfth update of the original article published in 1999 and brings coverage of the literature to the end of 2024.
David J. Harvey
wiley +1 more source
Selective Cross‐Metathesis of Highly Chelating Substrates in Aqueous Media
, 2020 The role of non-productive chelation in olefin metathesis has been investigated for a variety of highly functionalized substrates in aqueous environment.
Brian J. J. Timmer +6 more
core +1 more source
Kinetics of anionic polymerization of β‐myrcene in hydrocarbon solvents
Polymer International, EarlyView.The process of anionic polymerization of β‐myrcene in hydrocarbon solvents was examined by kinetic studies and quantum chemical calculations. Abstract The kinetics of anionic polymerization of β‐myrcene initiated by sec‐butyllithium were examined in saturated and unsaturated hydrocarbon solvents, i.e. cyclohexane, cyclohexene, 4‐vinylcyclohexene and dl‐
Alexander Rösler +4 more
wiley +1 more source
An Anthracene-Thiolate-Ligated Ruthenium Complex: Computational Insights into Z-Stereoselective Cross Metathesis. [PDF]
J Phys Chem A, 2023 Martínez JP, Trzaskowski B.
europepmc +1 more source
Exploiting the cross-metathesis reaction in the synthesis of pseudo-oligosaccharides
, 2009 An approach to the synthesis of pseudo-oligosaccharides based on the cross-metathesis reaction between distinct sugar-olefins, followed by intramolecular cyclization of the obtained heterodimer, is presented. In particular, the relative efficiency of two
S. Guglieri +4 more
core +1 more source