Stereoselective protecting group free synthesis of d,l-gulose ethyl glycoside via multicomponent enyne cross metathesis—hetero Diels–Alder reaction [PDF]
, 2009 An efficient and stereoselective synthesis of d,l-gulose was described. The key step of the synthetic route is represented by a multicomponent enyne cross metathesis—hetero Diels–Alder reaction which allows the formation of the pyran ring from cheap and ...
Aoyagi +22 more
core +1 more source
Synergistic approach to polycycles through Suzuki–Miyaura cross coupling and metathesis as key steps
Beilstein Journal of Organic Chemistry, 2018 This account provides an overview of recent work, including our own contribution dealing with Suzuki–Miyaura cross coupling in combination with metathesis (or vice-versa). Several cyclophanes, polycycles, macrocycles, spirocycles, stilbenes, biaryls, and
Sambasivarao Kotha +2 more
doaj +1 more source
Conversion of butanol to propene in flow: A triple dehydration, isomerisation and metathesis cascade
Catalysis Communications, 2022 A combined three-step flow cascade conversion of n-butanol to propene is demonstrated. Zeolite H-ZSM-5 gives high conversion in the initial n-butanol dehydration step (98%).
Yiping Shi +3 more
doaj +1 more source
Characterization and Dynamics of Substituted Ruthenacyclobutanes Relevant to the Olefin Cross-Metathesis Reaction [PDF]
, 2011 The reaction of the phosphonium alkylidene [(H_(2)IMes)RuCl2═CHP(Cy)_3)]^(+) BF_(4)^− with propene, 1-butene, and 1-hexene at −45 °C affords various substituted, metathesis-active ruthenacycles. These metallacycles were found to equilibrate over extended
Blake, Garrett +3 more
core +2 more sources
Straightforward Synthesis of α,β-Unsaturated Thioesters via Ruthenium-Catalyzed Olefin Cross-Metathesis with Thioacrylate [PDF]
, 2008 The cross-metathesis reaction of S-ethyl thioacrylate with a variety of olefins is effectively catalyzed by using a ruthenium benzylidene olefin metathesis catalyst.
Feringa, Ben L., +2 more
core +1 more source
Natural Product Communications, 2017 Metathesis reactions is firmly established as a valuable synthetic tool in organic chemistry, clearly comparable with the venerable Diels-Alder and Wittig reactions and, more recently, with the metal-catalyzed cross-coupling reactions.
Silvia Roscales, Joaquín Plumet
doaj +1 more source
Monotelechelic Poly(oxa)norbornenes by Ring-Opening Metathesis Polymerization Using Direct End-Capping and Cross-Metathesis [PDF]
, 2010 Two different methodologies for the synthesis of monotelechelic poly(oxa)norbornenes prepared by living ring-opening metathesis polymerization (ROMP) are presented.
Grubbs, Robert H., Matson, John B.
core +2 more sources
Synthesis of Tetrasubstituted Alkenes via Metathesis
Molecules, 2012 Fully substituted olefin generation via metathesis is presented. Catalyst development, optimization of reaction conditions and substrate screening are included.
Seung-Mann Paek
doaj +1 more source
Halide exchanged Hoveyda-type complexes in olefin metathesis
Beilstein Journal of Organic Chemistry, 2010 The aims of this contribution are to present a straightforward synthesis of 2nd generation Hoveyda-type olefin metathesis catalysts bearing bromo and iodo ligands, and to disclose the subtle influence of the different anionic co-ligands on the catalytic ...
Julia Wappel +6 more
doaj +1 more source
Genetic Incorporation of Olefin Cross-Metathesis Reaction Tags for Protein Modification.
Journal of the American Chemical Society, 2018 Olefin cross-metathesis (CM) is a viable reaction for the modification of alkene-containing proteins. Although allyl sulfide or selenide side-chain motifs in proteins can critically enhance the rate of CM reactions, no efficient method for their site ...
Bhaskar Bhushan +11 more
semanticscholar +1 more source