Cross metathesis of unsaturated epoxides for the synthesis of polyfunctional building blocks [PDF]
Beilstein Journal of Organic Chemistry, 2015 The cross metathesis of 1,2-epoxy-5-hexene (1) with methyl acrylate and acrylonitrile was investigated as an entry to the synthesis of polyfunctional compounds.
Meriem K. Abderrezak +6 more
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Modification of Polyhedral Oligomeric Silsesquioxanes (POSS) Molecules by Ruthenium Catalyzed Cross Metathesis [PDF]
Molecules, 2018 The scope of ruthenium (Ru)-catalyzed cross metathesis (CM) of allyl-decorated polyhedral oligomeric silsesquioxanes (POSS) was explored. A variety of different commercial and non-commercial ruthenium complexes were tested to determine that the nitro ...
Justyna Czaban-Jóźwiak +5 more
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Fast-Initiating, Ruthenium-based Catalysts for Improved Activity in Highly E-Selective Cross Metathesis [PDF]
Journal of the American Chemical Society, 2017 Ruthenium-based olefin metathesis catalysts bearing dithiolate ligands have been recently employed to generate olefins with high E-selectivity (>99% E) but have been limited by low to moderate yields.
Ahmed, Tonia S., Grubbs, Robert H.
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Ruthenium-Based Heterocyclic Carbene-Coordinated Olefin Metathesis Catalysts [PDF]
Chemical Reviews, 2010 The fascinating story of olefin (or alkene) metathesis (eq 1) began almost five decades ago, when Anderson and Merckling reported the first carbon-carbon double-bond rearrangement reaction in the titanium-catalyzed polymerization of norbornene.
Grubbs, Robert H. +1 more
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Direct synthesis of Z-alkenyl halides through catalytic cross-metathesis. [PDF]
Nature, 2016 Olefin metathesis has had a large impact on modern organic chemistry, but important shortcomings remain: for example, the lack of efficient processes that can be used to generate acyclic alkenyl halides.
Koh MJ +4 more
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Synthesis of a tyrosinase inhibitor by consecutive ethenolysis and cross-metathesis of crude cashew nutshell liquid [PDF]
Beilstein Journal of Organic Chemistry, 2018 A convenient and sustainable three-step synthesis of the tyrosinase inhibitor 2-hydroxy-6-tridecylbenzoic acid was developed that starts directly from the anacardic acid component of natural cashew nutshell liquid (CNSL).
Jacqueline Pollini +2 more
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Cross-metathesis of polynorbornene with polyoctenamer: a kinetic study [PDF]
Beilstein Journal of Organic Chemistry, 2015 The cross-metathesis of polynorbornene and polyoctenamer in d-chloroform mediated by the 1st generation Grubbs’ catalyst Cl2(PCy3)2Ru=CHPh is studied by monitoring the kinetics of carbene transformation and evolution of the dyad composition of polymer ...
Yulia I. Denisova +7 more
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A Stereoselective Enyne Cross Metathesis. [PDF]
ChemInform, 2003 AbstractFor Abstract see ChemInform Abstract in Full Text.
Lee, HY Lee, Hee Yoon +2 more
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Catalysis Communications, 2022 Stereoselective control of the cross metathesis of olefins is highly desired in synthetic procedures. In this work, guided by thermodynamic and kinetic descriptors calculated using density functional theory methods, we performed an exhaustive exploration
J. Pablo Martínez, Bartosz Trzaskowski
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Facile Synthesis of Effcient and Selective Ruthenium Olefin Metathesis Catalysts with Sulfonate and Phosphate Ligands [PDF]
, 2010 A series of novel, air-stable ruthenium NHC catalysts with sulfonate and phosphate anions have been prepared easily in one pot at high yields using commercially available precursors.
Grubbs, Robert H., Teo, Peili
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