Frontal polymerization-triggered simultaneous ring-opening metathesis polymerization and cross metathesis affords anisotropic macroporous dicyclopentadiene cellulose nanocrystal foam [PDF]
Communications Chemistry, 2022 Polymeric solid foams have several beneficial properties such as their light weight, thermal insulation or shock absorbance, but it is still challenging to efficiently control the foam architecture.
Jinsu Park, Seung-Yeop Kwak
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Relay cross metathesis reactions of vinylphosphonates [PDF]
Beilstein Journal of Organic Chemistry, 2014 Dimethyl (β-substituted) vinylphosphonates do not readily undergo cross metathesis reactions with Grubbs catalyst and terminal alkenes. However, the corresponding mono- or diallyl vinylphosphonate esters undergo facile cross metathesis reactions.
Raj K. Malla +2 more
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Equilibrium data for the cross-metathesis of methyl oleate with cinnamaldehyde [PDF]
Data in Brief, 2018 Here we present equilibrium data for the cross-metathesis of methyl oleate (MO) with cinnamaldehyde (CA) obtained experimentally from liquid-phase catalytic tests conducted at 323 K.
Pablo D. Nieres +2 more
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Synergistic approach to polycycles through Suzuki–Miyaura cross coupling and metathesis as key steps [PDF]
Beilstein Journal of Organic Chemistry, 2018 This account provides an overview of recent work, including our own contribution dealing with Suzuki–Miyaura cross coupling in combination with metathesis (or vice-versa). Several cyclophanes, polycycles, macrocycles, spirocycles, stilbenes, biaryls, and
Sambasivarao Kotha +2 more
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Cross metathesis of unsaturated epoxides for the synthesis of polyfunctional building blocks [PDF]
Beilstein Journal of Organic Chemistry, 2015 The cross metathesis of 1,2-epoxy-5-hexene (1) with methyl acrylate and acrylonitrile was investigated as an entry to the synthesis of polyfunctional compounds.
Meriem K. Abderrezak +6 more
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Supported Catalysts Useful in Ring-Closing Metathesis, Cross Metathesis, and Ring-Opening Metathesis Polymerization [PDF]
Polymers, 2016 Ruthenium and molybdenum catalysts are widely used in synthesis of both small molecules and macromolecules. While major developments have led to new increasingly active catalysts that have high functional group compatibility and stereoselectivity, catalyst/product separation, catalyst recycling, and/or catalyst residue/product separation remain an ...
Jakkrit Suriboot +2 more
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Modification of Polyhedral Oligomeric Silsesquioxanes (POSS) Molecules by Ruthenium Catalyzed Cross Metathesis [PDF]
Molecules, 2018 The scope of ruthenium (Ru)-catalyzed cross metathesis (CM) of allyl-decorated polyhedral oligomeric silsesquioxanes (POSS) was explored. A variety of different commercial and non-commercial ruthenium complexes were tested to determine that the nitro ...
Justyna Czaban-Jóźwiak +5 more
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Olefin cross metathesis based de novo synthesis of a partially protected L-amicetose and a fully protected L-cinerulose derivative [PDF]
Beilstein Journal of Organic Chemistry, 2014 Cross metathesis of a lactate derived allylic alcohol and acrolein is the entry point to a de novo synthesis of 4-benzoate protected L-amicetose and a cinerulose derivative protected at C5 and C1.
Bernd Schmidt, Sylvia Hauke
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Highly efficient conversion of plant oil to bio-aviation fuel and valuable chemicals by combination of enzymatic transesterification, olefin cross-metathesis, and hydrotreating [PDF]
Biotechnology for Biofuels, 2018 Background The production of fuels and chemicals from renewable resources is increasingly important due to the environmental concern and depletion of fossil fuel. Despite the fast technical development in the production of aviation fuels, there are still
Meng Wang +3 more
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Chemical upcycling of polybutadiene into size controlled α,ω-dienes and diesters via sequential hydrogenation and cross-metathesis. [PDF]
Chem SciVos C, Beckers I, O'Rourke G, De Vos D.
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