Results 31 to 40 of about 1,117,391 (197)

“Smelltronics”—From Gas to Smell Sensing

Advanced Materials, EarlyView.
The emerging field of smelltronics, encompassing sensing technologies for complex volatile organic compounds, holds significant potential for extracting valuable chemical information. It facilitates the noninvasive, real‐time monitoring of humans, food, and the environment.
Takeshi Ono, Tsunaki Takahashi, Jiangyang Liu, Haruka Honda, Zeng Jing, Wataru Tanaka, Takuro Hosomi, Takeshi Yanagida   +7 more
wiley   +1 more source

Organomagnesium Crown Ethers and Their Binding Affinities with Li+, Na+, K+, Be2+, Mg2+, and Ca2+ Ions - a Theoretical Study [PDF]

, 2021
Novel organomagnesium crown ether molecules have been computationally characterized for the first time using density functional theory (DFT). Monomer units of MgC6 have been used as building blocks. The potential energy surface of the parent elemental
Venkatesan S., Thimmakondu, Krishnan, Thirumoorthy, Uday Kumar, Padidela, Pothiappan, Vairaprakash   +3 more
core   +2 more sources

Synthesis and Characterization of Biocompatible Manganese‐Doped Titania Nanoparticles and Its Application to Single‐Cell Nanoencapsulation

Advanced Materials Interfaces, EarlyView.
Biocompatible Mn‐doped TiO2 nanozymes integrate TiO2 stability with Mn redox activity, enabling dopamine‐mediated cell‐surface polymerization and single‐cell nanoencapsulation while maintaining high colloidal stability, low ROS generation, and excellent cellular compatibility.
Filip Kozłowski, Nayoung Kim, Hyunwoo Choi, Geoffrey Daniel, Gulaim A. Seisenbaeva, Insung S. Choi, Vadim G. Kessler   +6 more
wiley   +1 more source

Periodic Trends in Actinyl Thio-Crown Ether Complexes [PDF]

Inorganic Chemistry, 2018
In-cavity complexes and their bonding features between thio-crown (TC) ethers and f-elements are unexplored so far. In this paper, actinyl(VI) (An = U, Np, Pu, Am, and Cm) complexes of TC ethers have been characterized using relativistic density functional theory.
Shu-Xian Hu, Jing-Jing Liu, John K. Gibson, Jun Li   +3 more
openaire   +3 more sources

Geometric and Electronic Structures of Ag⁺(benzo-18-crown-6), Ag⁺(dibenzo-18-crown-6), and Ag⁺(dibenzo-15-crown-5) Complexes Investigated by Cold Gas-Phase Spectroscopy

, 2019
The UV photodissociation (UVPD) spectra of Ag+ complexes with benzo-18-crown-6 (B18C6), dibenzo-18-crown-6 (DB18C6), and dibenzo-15-crown-5 (DB15C5) [Ag+(B18C6), Ag+(DB18C6), and Ag+(DB15C5)] are observed under cold gas-phase conditions.
Takayuki Ebata (1313994), Yuma Kitamura (7480610), Satoru Muramatsu (1747303), Motoki Kida (1555930), Yoshiya Inokuchi (1313997)   +4 more
core   +1 more source

The Preparatory (Anti)Bonding Character of Molecular Orbitals

Advanced Science, EarlyView.
Herein, a concept to qualitatively predict changes in bond dissociation energies upon reduction or oxidation of molecular compounds is introduced. Changing the population of so‐called preparatory molecular orbitals influences how molecular fragments are relaxing after bond cleavage, which is shown for isolated organometallic aluminum compounds as well ...
Jonas O. Wenzel, Johannes Werner, Pascal Weisenburger, Joachim Podlech, Ralf Köppe, Ingo Krossing, Dieter Fenske, Andreas Reiß, Claus Feldmann, Israel Fernández, Frank Breher   +10 more
wiley   +1 more source

Tailoring Structure–Property Relationships in π‐Conjugated Heterocyclic Poly(arylene alkylene) Anion‐Exchange Membranes for High‐Performance Water Electrolysis

Advanced Science, EarlyView.
From passive to active ion transport: π‐conjugated heterocycles reconfigure the hydration environment and microphase morphology of p‐terphenyl‐based anion‐exchange membranes, enabling fast hydroxide transport and high‐performance water electrolysis. ABSTRACT Anion‐exchange membrane water electrolysis (AEMWE) is a promising technology for sustainable ...
Qian Wang, Riyang Huang, Wenzhe Zhao, Si Chen, Yunpeng Guo, Yang Wu, Yun Zhao, Patric Jannasch, Jingshuai Yang   +8 more
wiley   +1 more source

Reconstructed Bi‐Sn Interfacial Sites Coupled with a Supramolecular Cation Cage Enable Low K+ Acidic CO2 Electroreduction to Formate

Advanced Energy Materials, EarlyView.
Pyrochlore‐derived Bi–Sn interfaces enable selective CO2 electroreduction to HCOOH in strongly acidic media (pH = 1). Interfacial electronic coupling promotes *OCHO formation while suppressing hydrogen evolution. Cryptand‐driven cation regulation enriches interfacial K+, maintaining high HCOOH faradaic efficiency of 94% even at low K+ electrolyte ...
Abdelmoniem H. Abu‐Ghazala, Xin Huang, Hsiwen Wu, Paul A. Webley, Shixia Chen, Jun Wang, Jie Zhang   +6 more
wiley   +1 more source

Supramolecular assembly of covalently modified Anderson-type polyoxometalates and crown ethers towards pseudo-rotaxane structures

Polyoxometalates
The supramolecular assembly of a series of covalently modified Anderson-type polyoxometalates (POMs) and 18-crown-6 ethers was investigated for the first time.
Yi-An Yin, Wu-Ji Chen, Chun-Yan Liu, Meng-Meng Zhang, Chang-Gen Lin, Haralampos N. Miras, Yu-Fei Song   +6 more
doaj   +1 more source

Complexation of Hydronium Ion with Several Crown Ethers in Nitromethane Solution [PDF]

Iranian Journal of Chemistry & Chemical Engineering, 1992
The interaction between hydronium ion and several crown ethers was studied via conductometry in nitromethane at 25 °C and 1H-NMR techniques. The stabilities of the resulting 1:1 complexes were determined from the conductance data and found to vary in the
Mihammad Kazem Amini
doaj