Results 141 to 150 of about 2,487,426 (273)
Reactions of Terminal Olefins With Iron Carbenes
Iron carbenes react with terminal olefins and show productive metathesis or metathesis‐divergent pathways depending on the nature of the olefin. Reactions proceed through 2π + 2π cycloadditions to generate transient metallacyclobutane intermediates that undergo cycloreversion to generate the metathesis product or the metathesis‐divergent β‐hydride ...
Zachary S. Lincoln +2 more
wiley +2 more sources
Droplet-on-demand tape drive and X-ray emission spectroscopy prototypes for time-resolved serial crystallography on VMXi at Diamond Light Source. [PDF]
Aller P +27 more
europepmc +1 more source
Suppression of Peierls Instability in a Metal−Halide Porous Framework
Peierls distortion in one‐dimensional Pt‐I chains is suppressed by confinement within the periodic electrostatic environment of a porous Cu–I framework. X‐ray crystallography shows equivalent Pt–I distances without bond alternation, and conductivity of the Pt‐I chains is greatly enhanced.
Ning Zhou +3 more
wiley +2 more sources
A model for crystallography engagement with children in early elementary school with activities and book development. [PDF]
Marr ZY, Wong J, Stieber SCE.
europepmc +1 more source
Automated macromolecular model building for X-ray crystallography using ARP/wARP version 7
G. Langer +3 more
semanticscholar +1 more source
Modular access to underexplored C5‐sulfenyl thiazoles via an intermolecular Pummerer rearrangement is reported. The methodology exhibits a broad functional group tolerance enabling the seamless design of trisubstituted thiazole cores bearing a sulfur handle for further elaboration.
Joe L. Smy +5 more
wiley +2 more sources
Cancer stem cells (CSCs) drive metastasis, relapse and resist conventional apoptosis‐inducing chemotherapies. We report a cobalt(III)‐cyclam complex with pyrene and diflunisal moieties that reduces the viability of breast CSCs at low micromolar concentrations.
Jiaxin Fang +7 more
wiley +2 more sources
TADF‐Active Tetrazole Luminophores for Visible‐Light Functionalization of Nanoparticles and Surfaces
A series of tetrazoles are reported that undergo 1,3‐dipolar cycloadditions with alkene and alkyne substrates, generating (dihydro)pyrazole products that exhibit thermally activated delayed fluorescence (TADF). The “photo‐click” reactivity of these tetrazoles is leveraged to functionalize nanoparticles and surfaces with TADF‐active chromophores ...
Ryoga Hojo +11 more
wiley +2 more sources

