Results 181 to 190 of about 287,848 (276)

Probing Solution Dynamics of Tissue Factor Using Molecular Dynamics Simulations Guided by NMR Chemical Shifts. [PDF]

J Phys Chem B
Lihan M, Pant S, Ojoawo AM, Rienstra CM, Tajkhorshid E.   +4 more
europepmc   +1 more source

Hydrogen Atom Transfer: An Intramolecular Main‐Group Metal‐Ligand Cooperative Biradical Pathway

Chinese Journal of Chemistry, EarlyView.
The molecular system consisting of a main‐group metal and a redox‐active ligand, ((2,6‐iPr2C6H3)NC(Me))2AlCl(THF), has been shown to react with azides and diazomethanes, yielding products through both a biradical intermediate and a hydrogen atom transfer process.
Ting Chen, Shaoying Ju, Rui Wei, Weili Yan, Yufen Zhao, Douglas W. Stephan, Yile Wu   +6 more
wiley   +1 more source

PEO-sheathed liquid jets increase sample delivery stability for serial femtosecond X-ray crystallography. [PDF]

Sci Rep
Vakili M, Bajt S, Bielecki J, Botha S, Cerniglia C, Chapman HN, Deiter C, de Wijn R, Dörner K, E J, Fromme P, Fromme R, Gañán Calvo AM, Han H, Huynh PBN, Kim C, Kloos M, Koua FHM, Letrun R, Meza-Aguilar JD, Montanero JM, Morin K, Popelar T, Rubio González A, Schmidt C, Sharma S, Sobolev E, Tseng JT, Turkot O, Wrona A, Yang JH, Yogaganeshan G, Bean R.   +32 more
europepmc   +1 more source

Xylose Acetals ‐ a New Class of Sustainable Solvents and Their Application in Enzymatic Polycondensation

ChemSusChem, Volume 18, Issue 6, March 15, 2025.
Novel organic solvents with an unmodified carbohydrate core were synthesised both from D‐xylose and directly from biomass and were successfully used as reaction media for lipase biocatalysts to synthesise aliphatic and aromatic polyesters. Abstract The use of organic solvents in academic research and industry applications is facing increasing ...
Anastasia O. Komarova, Cicely M. Warne, Hugo Pétremand, Laura König‐Mattern, Johannes Stöckelmaier, Chris Oostenbrink, Georg M. Guebitz, Jeremy Luterbacher, Alessandro Pellis   +8 more
wiley   +1 more source

Structural insights into RNase H catalytic mechanism from room-temperature X-ray and neutron crystallography of apo- and RNA/DNA hybrid-bound enzyme. [PDF]

Curr Res Struct Biol
Gerlits O, Collins A, Kovalevsky A.
europepmc   +1 more source

Gold(I) Phosphine/Phosphido‐Borohydride Complexes

European Journal of Inorganic Chemistry, EarlyView.
Synthesis, structure, and electrochemical characteristics of a homologous series of gold(I) complexes featuring phosphine and phosphido–borohydride ligands. A homologous series of linear, mononuclear gold(I) phosphine/phosphido‐borohydride complexes, encompassing [Au(PR3)2]+ 1, [Au(PR3)(PR2BH3)] 2 and [Au(PR2BH3)2]– 3 (R = tBu, Ad), has been prepared ...
Matthew J. G. Sinclair, Marc‐Etienne Moret, Luke A. Wilkinson, Adrian B. Chaplin   +3 more
wiley   +1 more source

Breaking barriers: transitioning from X-ray crystallography to cryo-EM for structural studies. [PDF]

Acta Crystallogr D Struct Biol
Zafar H, Malone KL, Singh AK, Cianfrocco MA, Glass KC.   +4 more
europepmc   +1 more source

Unexpected Products Isolated From Neptunium Halide Syntheses

European Journal of Inorganic Chemistry, EarlyView.
Unanticipated products can crystallize when doing ligand substitution chemistry of NpCl4(DME)2 (DME = 1,2‐dimethoxyethane). Dissolution of NpCl4(DME)2 in CDCl3 can recrystallize the dimer [NpCl3(μ‐Cl)(DME)]2. The presence of hydroxylammonium from oxidation state adjustment can result in the isolation of (NH3OH)2[NpCl6]•3(1,4‐dioxane). The contamination
Megan A. Whitefoot, Joseph M. Sperling, Matthias Zeller, Suzanne C. Bart   +3 more
wiley   +1 more source

Modelling of radiation damage and beam-induced heating of room-temperature samples at extremely high flux MX beamlines. [PDF]

IUCrJ
Appleby MV, Kepa MW, Winter G, McAuley KE, Beale JH.   +4 more
europepmc   +1 more source

Phosphorescent Platinum(II) Complexes With Diazinedipyrrolide Pincer Ligands: Structure and Photophysical Properties

European Journal of Inorganic Chemistry, EarlyView.
A new family of phosphorescent Pt(II) complexes with pyrimidinedipyrrolide ligands, including a pyrazine analog, was designed and synthesized. Their emission properties can be finely tuned via ligand modification, revealing strong phosphorescence originating from intraligand charge transfer transitions.
Marcela Horáková, Alexandre Rico, Filip Bureš, Pascal le Poul, Sébastien Gauthier, Jiří Váňa, Zdeňka Růžičková, Sylvain Achelle   +7 more
wiley   +1 more source