Results 231 to 240 of about 2,064,816 (279)

Xanthopinacol Boronate: A Robust, Photochemically Assembled and Cleavable Boronic Ester for Orthogonal Chemistry

open access: yesAngewandte Chemie, EarlyView.
Xanthopinacol (xpin) boronates are a conceptually new class of masked boronic acids designed to alleviate many of the disadvantages of pinacol esters and other popular adducts. They can be formed directly from xanthone and UV light, undergo orthogonal transformations, and are cleavable under photoredox catalysis or oxidative conditions that recycle ...
David M. Heard   +2 more
wiley   +1 more source

Watching proteins function with time-resolved x-ray crystallography

open access: yesJournal of physics D: Applied physics, 2017
V. Šrajer, Marius Schmidt
semanticscholar   +1 more source

Enantiomerically Enriched Aziridine‐2‐carboxylates via Copper‐Catalyzed Reductive Kinetic Resolution of 2H‐Azirines

open access: yesAngewandte Chemie International Edition, Accepted Article.
We present the first reductive kinetic resolution of racemic 2H‐azirines to prepare optically enriched N‐H aziridine‐2‐carboxylates, which are bench stable and easily diversifiable building blocks, concomitantly with the corresponding enantiomerically enriched 2H‐azirines. The N‐H aziridines were obtained with excellent diastereoselectivity (>20:1) and
Yinuo Zheng   +3 more
wiley   +1 more source

Self‐optimizing Cobalt Tungsten Oxide Electrocatalysts toward Enhanced Oxygen Evolution in Alkaline Media

open access: yesAngewandte Chemie International Edition, EarlyView.
Progressively enhanced oxygen evolution is achieved by self‐optimization of cobalt tungsten oxide deposited on lab‐synthesized copper oxide substrate. Experimental data proved dynamic compositional / structural evolution while theoretical calculation revealed active site adaptation.
Christean Nickel   +16 more
wiley   +1 more source

Protonated Glutamate and Aspartate Side Chains Can Recognize Phosphodiester Groups via Strong and Short Hydrogen Bonds in Biomacromolecular Complexes

open access: yesAngewandte Chemie International Edition, Accepted Article.
Phosphodiester groups occur ubiquitously in nature, e.g. in nucleic acids or in cyclic (di‐)nucleotides important for signal transduction. Proteins often use polar or positively charged amino acids to interact with the negatively charged phosphodiester groups via hydrogen bonds and salt bridges.
Jens Wöhnert   +5 more
wiley   +1 more source

The Flexibility of Tetra(N‐Heterocyclic Carbene) Ligands Controls the Nuclearity and Geometry of Polynuclear MI‒NHC Assemblies

open access: yesAngewandte Chemie International Edition, Accepted Article.
A series of tetrakisimidazolium salts bearing two di(phenylimidazolium)amine groups linked by differently substituted anthracenes has been prepared. These are H4‐1a(PF6)4 (anthracene bridge), H4‐1b(PF6)4 (phenyl‐anthracene‐phenyl bridge), H4‐1c(PF6)4 (anthracene‐phenyl bridge) and H4‐1d(PF6)4 (anthracene‐phenyl‐anthracene bridge). X‐ray crystallography
Guang-Feng Jin   +3 more
wiley   +1 more source

Decoding Variants of Pyrite, Arsenopyrite, and Marcasite Using an Electron Counting Rule

open access: yesAngewandte Chemie International Edition, EarlyView.
A new ‘structure determining electron’ (SDE) rule allows identifying marcasite (M), arsenopyrite (A), and pyrite (P) related compounds based on the electron distribution around transition metals. It offers a framework for categorising structural variants as compounds with M, A, and P layers. Nine new ternary representatives, including the first to show
Kristian Witthaut   +2 more
wiley   +1 more source

Coordinative Ring‐Opening Polymerization of Limonene Carbamate towards Phosgene‐ and Isocyanate‐Free Polyurethane

open access: yesAngewandte Chemie International Edition, Accepted Article.
This study presents a phosgene‐ and isocyanate‐free route for the synthesis of polyurethanes using (R)‐limonene as a bio‐based starting material. The synthesis of the cyclic limonene‐based carbamate monomer LU is achieved in high yields using dimethyl carbonate as a sustainable, less hazardous phosgene surrogate and is verified by NMR, SC‐XRD, ESI‐MS ...
Jonas Futter   +4 more
wiley   +1 more source

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