Superoxide reductase from Giardia intestinalis: structural characterization of the first sor from a eukaryotic organism shows an iron centre that is highly sensitive to photoreduction [PDF]
Superoxide reductase (SOR), which is commonly found in prokaryotic organisms, affords protection from oxidative stress by reducing the superoxide anion to hydrogen peroxide.
Bandeiras, Tiago M.+8 more
core +2 more sources
Laser‐Induced Graphene from Waste Almond Shells
Almond shells, an abundant agricultural by‐product, are repurposed to create a fully bioderived almond shell/chitosan composite (ASC) degradable in soil. ASC is converted into laser‐induced graphene (LIG) by laser scribing and proposed as a substrate for transient electronics.
Yulia Steksova+9 more
wiley +1 more source
O- vs. N-protonation of 1-dimethylaminonaphthalene-8-ketones: formation of a peri N–C bond or a hydrogen bond to the pi-electron density of a carbonyl group [PDF]
X-ray crystallography and solid-state NMR measurements show that protonation of a series of 1-dimethylaminonaphthalene-8-ketones leads either to O protonation with formation of a long N–C bond (1.637–1.669 Å) between peri groups, or to N protonation and ...
Allen+39 more
core +2 more sources
This work describes a novel approach to obtain composite submicrometric structures of nickel hexacyanoferrate integrating trigonal selenium with the aim of enhancing the catalytic efficiency in oxygen evolution reaction (OER). Interestingly, the nanostructures undergo a cube‐to‐sphere transition that optimizes surface properties, leading to superior ...
Edlind Lushaj+10 more
wiley +1 more source
Crystal structure of 2-(1,3-dioxoindan-2-yl)isoquinoline-1,3,4-trione
In the title isoquinoline-1,3,4-trione derivative, C18H9NO5, the five-membered ring of the indane fragment adopts an envelope conformation with the nitrogen-substituted C atom being the flap. The planes of the indane benzene ring and the isoquinoline-1,3,
Raza Murad Ghalib+4 more
doaj +1 more source
This study demonstrated single‐crystalline PbTiO3‐based memristors with atomically sharp interfaces, well‐ordered lattices, and minimal lattice mismatch. The devices exhibited an ON/OFF ratio exceeding 105, high stability, and rich resistance‐state modulation.
Haining Li+7 more
wiley +1 more source
Synthesis and coordination chemistry of 2-(di-2-pyridylamino)pyrimidine; structural aspects of spin crossover in an Fe(II) complex [PDF]
This paper was accepted on February 26 20122-(Di-2-pyridylamino)pyrimidine (L), a potentially ditopic tetradentate ligand, was synthesized from commercially available di-2-pyridylamine and 2-chloropyrimidine.
Addison+38 more
core +2 more sources
Computational Modeling of Reticular Materials: The Past, the Present, and the Future
Reticular materials are advanced materials with applications in emerging technologies. A thorough understanding of material properties at operating conditions is critical to accelerate the deployment at an industrial scale. Herein, the status of computational modeling of reticular materials is reviewed, supplemented with topical examples highlighting ...
Wim Temmerman+3 more
wiley +1 more source
Crystal engineering with 2,2':6',2"- terpyridine derivatives and their metal complexes : from simple building blocks to coordination polymers and networks [PDF]
This thesis concerns the design of ligands for use in the construction of larger supramolecular systems, with emphasis on the application of 4'-substitured 2,2',6',2''- terpyridine ligands and their iron(II) and ruthenium(II) complexes in crystal ...
Beves, Jonathon Edward
core +1 more source
Supramolecular Chemistry in Metal–Organic Framework Materials
This review highlights synergies between reticular chemistry and supramolecular chemistry. The role of supramolecular interactions in determining framework…guest interactions and attempts to understand dynamic behavior in metal–organic frameworks (MOFs), particularly emphasizing the development of crystal sponges, studying reactions in frameworks and ...
Eugenia Miguel‐Casañ+3 more
wiley +1 more source