Results 211 to 220 of about 412,410 (289)

Grown by Crystallography and Grow Crystallography

Nihon Kessho Gakkaishi, 2014
openaire   +2 more sources

Alkali‐Metal Base Catalyzed Electrocyclization of Isoprene Derivatives

Chemistry – A European Journal, EarlyView.
Simple and abundant alkali‐metal base catalysis in combination with Lewis basic polyamines enables the electrocyclization of isoprene‐derived trienes to cycloheptadienes under neat conditions. Mechanistic insight supported by DFT guides a scalable route to seven‐membered carbocycles which, after reduction, give saturated cycloalkanes relevant as ...
Mikaël Le Roch, Krzysztof Piech, Aurélien Crochet, Andreu Tortajada   +3 more
wiley   +1 more source

Author Correction: Enantioselective construction of inherently chiral pillar[5]arenes via palladium-catalysed Suzuki-Miyaura cross-coupling. [PDF]

Nat Commun
Luan TR, Sun C, Tian YL, Jiang YK, Xi LL, Liu RR.   +5 more
europepmc   +1 more source

Stereoselective Higher‐Order [10+4]‐ and [10+6] Cycloadditions Between Two Highly Unsaturated and Ambiphilic π‐Addends

Chemistry – A European Journal, EarlyView.
Aminocatalytically generated isobenzofulvenes and 3‐oxidopyridinium betaines act as ambiphilic reaction partners in orbital‐symmetry‐allowed [10+4] cycloadditions or formally symmetry‐forbidden concerted thermal [10+6] cycloadditions. The reaction furnishes three cycloadducts: one [10+4] cycloadduct and two regioisomeric [10+6] cycloadducts.
Jonas Faghtmann, Anne Kristensen, Fabien Fritz, Signe Sofie Pladsbjerg Andresen, Anne Rask Østergaard, Johannes Nygaard Lamhauge, K. N. Houk, Karl Anker Jørgensen   +7 more
wiley   +1 more source

Amine Tris(phenolate) Ligands as a Versatile Scaffold for Early and Late Transition Metals: Synthesis and Application. [PDF]

ACS Omega
Kumari N, Singh RK, Mongal BN, Dwivedi A, Dixit P, Pandey AK.   +5 more
europepmc   +1 more source

Antisolvent crystallization of lithium hydroxide monohydrate: Significant factors and kinetics analysis

The Canadian Journal of Chemical Engineering, EarlyView.
Abstract Crystallization is the final stage in lithium hydroxide monohydrate (LiOH · H2O) production, and antisolvent crystallization offers a lower‐energy route compared with evaporative methods. In this study, we investigated bench‐scale ethanol‐based antisolvent crystallization of LiOH · H2O, and identified the significant impact parameter via a ...
Chentao He, Liuyin Xia
wiley   +1 more source

Coupled on-line in crystallo UV-Vis absorption spectroscopy and X-ray crystallography to compare specific radiation damage in metal-containing proteins at room versus cryogenic temperature. [PDF]

Acta Crystallogr D Struct Biol
Caramello N, Rose SL, Mathieu E, Petit L, Tews I, Engilberge S, Royant A.   +6 more
europepmc   +1 more source

Clathrate hydrate crystallization

The Canadian Journal of Chemical Engineering, EarlyView.
Abstract Clathrate hydrate crystallization has been an area of interest to chemical engineers from the point of view of crystal structure, thermophysical properties, phase equilibria, kinetics, industrial applications, and environmental (climate change) implications.
Peter Englezos
wiley   +1 more source

AlphaFold as a prior: experimental structure determination conditioned on a pretrained neural network. [PDF]

Nat Methods
Fadini A, Li M, McCoy AJ, Banjara S, Okumura H, Napier E, Fontana P, Khan AR, Jovine L, Terwilliger TC, Read RJ, Hekstra DR, AlQuraishi M.   +12 more
europepmc   +1 more source

Hydrogen Atom Transfer: An Intramolecular Main‐Group Metal‐Ligand Cooperative Biradical Pathway

Chinese Journal of Chemistry, EarlyView.
The molecular system consisting of a main‐group metal and a redox‐active ligand, ((2,6‐iPr2C6H3)NC(Me))2AlCl(THF), has been shown to react with azides and diazomethanes, yielding products through both a biradical intermediate and a hydrogen atom transfer process.
Ting Chen, Shaoying Ju, Rui Wei, Weili Yan, Yufen Zhao, Douglas W. Stephan, Yile Wu   +6 more
wiley   +1 more source