Results 221 to 230 of about 9,376 (302)

Programmable Solid‐Electrolyte Interfaces for Efficient and Selective Electrochemical Hydrogenations

open access: yesAngewandte Chemie, EarlyView.
Poly(ionic liquid) binders are shown to actively control the electrode microenvironment, strongly enhancing electrochemical hydrogenation compared to traditional binders. The work redefines the binder as an active component of catalytic electrode design, reshaping local potential gradients and interfacial ion distribution to modulate adsorbed H ...
Anastasios Orestis Grammenos   +9 more
wiley   +1 more source

Fundamental Understanding of Oxidative Stability in Fluorinated Asymmetric Ethers for Li Batteries

open access: yesAngewandte Chemie, EarlyView.
To improve Li‐metal battery electrolytes, we analyze fluorinated 1‐ethoxy‐2‐methoxyethane (FxEME) oxidative stability via density functional theory (DFT) and molecular dynamics (MD). Fluorination strengthens ethoxy C–H bonds and alters solvent orientation at the cathode, weakening interfacial interactions.
Liang‐Ting Wu   +3 more
wiley   +1 more source

Pd/C‐Catalyzed Hydrogenation of CF3‐, CF2H‐, and CF2CO2Et‐containing Pyridines: A Robust Method for Highly Functionalized containing Piperidines

open access: yesAngewandte Chemie, EarlyView.
A robust and efficient method to access diversely functionalized fluorinated piperidines was developed. The approach features the hydrogenation of polysubstituted pyridines bearing CF3, CF2H, and CF2CO2Et substituents using an inexpensive, readily available heterogeneous Pd/C catalyst under air‐ and moisture‐tolerant conditions, offering an appealing ...
Thibaud Charvillat   +7 more
wiley   +1 more source

Integration of 3D-printed simulation models into a PAG fellowship curriculum: impact on trainee confidence and curriculum acceptability. [PDF]

open access: yesFront Med (Lausanne)
Dumont T   +8 more
europepmc   +1 more source

Generation of the Camptothecin Scaffold by a Flavin‐Catalyzed Photooxidative Skeletal Reorganization

open access: yesAngewandte Chemie, EarlyView.
The biosynthetic pathway of the anticancer drug precursor camptothecin involves an enigmatic skeletal reorganization from a 6/5/6 tetrahydro‐β‐carboline to a 6/6/5 pyrroloquinoline ring system. Here, we show that this transformation can be achieved by photooxidation with flavin cofactors, such as flavin mononucleotide (FMN) as catalysts.
Shenyu Liu   +6 more
wiley   +1 more source

Ketazine‐Linked Covalent Organic Framework for Metal‐Free Electrocatalytic Nitrate‐to‐Ammonia Conversion

open access: yesAngewandte Chemie, EarlyView.
A metal‐free fluorinated ketazine‐linked COF is introduced as an efficient electrocatalyst for nitrate reduction to ammonia under neutral conditions. Fluorine substitution enhances π–π stacking and crystallinity, enabling a Faradaic efficiency of 59.9% and an NH3 yield rate of 1639.9 µmol h−1 mgCOF−1 at −0.9 V versus RHE. This establishes an unexplored
Islam E. Khalil   +12 more
wiley   +1 more source

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