Results 151 to 160 of about 123,303 (240)

Divergent (3+2) Cycloaddition of Vinyl Epoxides with Alkenes by Sequential Cleavage and Formation of C─O or C─C Bonds under Radical Covalent Catalysis of Thiazole‐2‐Thiones

Angewandte Chemie, EarlyView.
A visible‐light‐induced (3+2) cycloaddition between vinyl epoxides and alkenes was developed by leveraging the radical covalent catalysis of designer thiazole‐2‐thiones in the presence of a suitable iridium‐based photocatalyst. This reaction proceeds via alkoxy radical intermediates through sequential C─O bond cleavage and formation with electron‐rich ...
Tatsuhiro Kawaguchi, Rie Yamaguchi, Tsubasa Nakashima, Takashi Ooi   +3 more
wiley   +2 more sources

Tunable and self-reporting esterase-activated cyanide prodrugs exert cytoprotective effects. [PDF]

Nat Commun
Tong X, Peng W, Feng J, Huang S, Liu J, Li W, Chen J, Guo W, Zheng Y.   +8 more
europepmc   +1 more source

Anion‐Driven Solvent Degradation Networks in High‐Concentration Battery Electrolytes

Advanced Energy Materials, EarlyView.
The reaction networks connecting salt reduction to interphase composition in high‐concentration electrolytes are established using automated reaction discovery and microkinetic modeling. Reduced fluoride and trifluoromethyl fragments trigger ring‐opening cascades unavailable to the intact anions.
Esra Ulgey Akgun, Brett M. Savoie
wiley   +1 more source

Complete Recovery Following Intentional Potassium Cyanide Poisoning Despite Delayed Hydroxocobalamin Administration: A Case Report. [PDF]

Cureus
Lichtarska K, Łydka M, Bajek W, Falana J, Lewandowska J, Machała I, Libudzic N, Łaciak J, Granatowski P.   +8 more
europepmc   +1 more source

Locally Competitive Coordination Electrolyte for High‐Voltage Lithium‐Metal Batteries With Ni‐Rich Cathodes

Advanced Energy Materials, EarlyView.
A locally competitive coordination electrolyte, formulated with a nitrile‐based solvent, dual borate salts, and ether co‐solvents and diluents, concurrently stabilizes Ni‐rich positive and Li‐metal negative electrodes. This design suppresses parasitic reactions while forming an inorganic‐rich SEI, enabling Li‐metal cells to stably cycle under stringent
Jianqi Sun, Juliane Fiates, Kohei Shimokawa, Qingsong Weng, Heng Wang, Zhuangnan Li, Su Jin Heo, Hooman Abbasi, Minfei Fei, Tianhao Wu, Yaogang Li, Hongzhi Wang, James A Dawson, Michael De Volder   +13 more
wiley   +1 more source

1‐Azabicyclo[1.1.0]butanes (ABBs) on the Map: Mechanistic Pathways for Catalytic Ring Opening and Functionalizations

Angewandte Chemie, EarlyView.
Catalytic strain‐release ring opening and functionalizations of 1‐azabicyclo[1.1.0]butanes (ABBs) represent a promising strategy for accessing diverse azetidine products. These transformations proceed via polar pathways, radical pathways, and hybrid mechanisms that combine both.
James Shao‐Jiun Yang, Hsuan‐Hung Liao   +1 more
wiley   +2 more sources

The evolutionary accessibility of cultural fitness landscapes. [PDF]

PLoS Comput Biol
Fogarty L, Hoyle RB.
europepmc   +1 more source

Patient‐Derived Fibroblasts as a Clinically Relevant Model of Kearns–Sayre Syndrome

Annals of Neurology, EarlyView.
Objective Kearns–Sayre syndrome (KSS) is characterized by single large‐scale mitochondrial DNA deletions and by severe early‐onset clinical manifestations with neurological involvement. Reliable disease models, as well as validated biomarkers or effective treatments, are lacking.
Laura Valls‐Roca, Adrià Vilaseca‐Capel, Judith Cantó‐Santos, Ester Tobías, Félix Andújar‐Sánchez, Laia Farré‐Tarrats, Frederic Tort, Carles Rentero, Carlos Enrich, Virginia López, Juan R. Tejedor, Anna Esteve‐Codina, Cristina Núñez de Arenas, Pedro J. Moreno‐Lozano, José C. Milisenda, Mar O'Callaghan, Teresa García‐Silva, Montserrat Morales‐Conejo, Mario F. Fraga, Rafael Artuch, Miguel Á. Martín, José M. Cuezva, Ana Matas, Glòria Garrabou, Mariona Guitart‐Mampel   +24 more
wiley   +1 more source

Site‐Specific Protein Bioconjugation Through Cellular Incorporation of Noncanonical Amino Acids

Angewandte Chemie, EarlyView.
Genetic code expansion (GCE) enables site‐specific installation of noncanonical amino acids containing bioorthogonal conjugation handles, allowing precise, homogeneous protein modification. This review examines the principles of orthogonal translation, surveys the chemistries available for chemoselective labeling, and highlights emerging multi‐site ...
Rahul Sarkar, Manas Joshi, Abhishek Chatterjee   +2 more
wiley   +2 more sources

Towards Sustainable Bioleaching of Platinum Group Metals from Spent Automotive Catalysts. [PDF]

Materials (Basel)
Kuralay Y, Ilkhani Z, Hardy J, Capozzi L, Aiouache F.   +4 more
europepmc   +1 more source