An Alkali Amide Approach to Triphosphabenzenes
Alkali metal amides offer a simple route to phosphorus aromatics. LiNMe2 catalyzes [2+2+2] cyclotrimerization of a phosphaalkyne, while tetrahydrofuran (THF) stabilizes a λ4‐triphosphabenzene anion intermediate. Using KN(SiMe3)2 switches reactivity to arene C(sp3)─H activation, giving benzylated λ4‐triphosphabenzenes and rare λ5‐triphosphabenzenes ...
Owen J. Jones +2 more
wiley +1 more source
Pharmacokinetics and Efficacy of a Cyanide-Neutralizing [Mo<sub>2</sub>O<sub>2</sub>(µ-S)<sub>2</sub>]<sup>2+</sup> Based Metallodrug in NMRI Mice. [PDF]
Hancock LA, Eiriksdottir B, Suman SG.
europepmc +1 more source
Three in one fluorescent sensing and imaging of chemical warfare agents. [PDF]
Liu J +9 more
europepmc +1 more source
Core-Regenerating Atom-Pair Exchange Enables Skeletal Carbon Isotope Incorporation into Pyridines. [PDF]
Han J, Jacobsen EA, Zhang YA.
europepmc +1 more source
A Highly Selective Hemicyanine-Based Turn-Off Fluorescent Sensor for Cyanide Detection in Food Samples. [PDF]
Gokbel F +4 more
europepmc +1 more source
Synthesis of Aminocyclopropanes by Redox‐Neutral Aminoalkylation
Aminocyclopropane synthesis by hydroaminoalkylation utilizing cheap, readily available starting materials is presented, offering orthogonality to commonly used methods and allowing broad functional‐group tolerance. Solvent‐mediated conditions enable the reaction of a pre‐formed hemiaminal with alkenes and alkynes.
Gwyndaf A. Oliver +6 more
wiley +1 more source
Expanding Cyanide-Bridged Weakly Coordinating Anions Through the Brominated Silver Salt Ag[BCNB<sup>Br</sup>]. [PDF]
Moshtaha AL +4 more
europepmc +1 more source
The Matador Bug and Several Related Leaf-footed Bugs (Hemiptera: Coreidae) Accumulate Cyanogens From their Host Plants. [PDF]
Morrison CR +4 more
europepmc +1 more source
Unraveling the active site cover of coproheme decarboxylase from Listeria monocytogenes. [PDF]
Falb N +4 more
europepmc +1 more source

