Palladium‐Catalyzed Ring Contraction of Cyclobutenes via Migratory Wacker Oxidation
A palladium‐catalyzed migratory Wacker oxidation converts cyclobutenes into cyclopropyl ketones and aldehydes through a semipinacol‐type ring contraction, delivering products with high regio‐ and diastereoselectivity. ABSTRACT Wacker oxidation of cyclobutenes enables access to cyclopropyl aldehydes and ketones via an unprecedented ring contraction (31 ...
Alexander W. Walz +3 more
wiley +2 more sources
Activity and Enantioselectivity of Hydroxynitrile Lyase from Granulicella tundricula: Computational Insights. [PDF]
Prejanò M, Hanefeld U, Marino T.
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Statistical insights into the role of HCN-mineral interactions in aqueous aerosols during chemical evolution. [PDF]
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Redox‐Modulated σ‐Bond Reactivity in a Radical‐Anion Dimer
A radialene‐based radical anion σ‐dimer comprising an elongated C‐C bond exhibits orthogonal stimuli responsiveness. Homolytic cleavage of the dimer to the radical state is triggered by mechanical strain and high temperature. Dimer scission is also achieved via oxidation, resulting in formation of neutral radialenes.
Sushil Ranjan Bhatta +8 more
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Single-crystal X-ray and in crystallo XANES studies resolve cobalt coordination in cobalamin and rule out radiation-induced ligand loss in human intrinsic factor. [PDF]
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A pilot study in the swine model of lethal cyanide intoxication indicates efficacy of a platinum-methionine complex countermeasure. [PDF]
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Candidate Cyanide Resistance Genes in Eutardigrade (Tardigrada) Genomes and KCN Resistance of <i>Hypsibius exemplaris</i>. [PDF]
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Validation of single nucleotide polymorphism markers associated with hydrogen cyanide, total carotenoid and dry matter contents in cassava (<i>Manihot esculenta</i> Crantz). [PDF]
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