Results 261 to 270 of about 39,245 (323)

Wacker Oxidation of Trisubstituted Alkenes: Pd(II)‐Catalyzed Oxidative Ring Expansion of Exocyclic α,β‐Unsaturated Carbonyl to 2‐Fluoro‐1,3‐Dicarbonyl Compounds

Angewandte Chemie, EarlyView.
First examples of Pd(II)‐catalyzed Wacker oxidation of trisubstituted alkenes, coupled with electrophilic fluorination, enable a one‐carbon ring expansion of exocyclic α,β‐unsaturated carbonyls to 2‐fluoro‐2‐acyl‐cycloalkanones. Abstract The Wacker oxidation is a powerful synthetic method widely employed for the transformation of monosubstituted ...
Vincent Goëlo, Qian Wang, Jieping Zhu
wiley   +1 more source

Durability characteristics of geopolymer concrete produced using gold ore tailings along with recycled coarse aggregates. [PDF]

Sci Rep
Lokesha EB, Aruna M, Reddy SK.
europepmc   +1 more source

THE EFFECTS OF POTASSIUM CYANIDE, POTASSIUM ARSENITE, AND ETHYL URETHANE ON RESPIRATION IN PELOMYXA CAROLINENSIS

, 1944
D. M. Pace, W. H. Belda
openalex   +2 more sources

Radical Ring‐Opening Reaction of Non‐Activated Oximes Catalyzed by Aldoxime Dehydratases

Angewandte Chemie, EarlyView.
A novel catalytic mode of aldoxime dehydratases for the abiotic radical ring‐opening reaction of cyclic ketoximes is reported. Aldoxime dehydratase from Nocardioides simplex was found to efficiently generate iminyl radicals from challenging “non‐activated” cycloketone oximes and to promote radical ring‐opening reactions to produce γ‐ and ε‐sulfinylated
Shunsuke Kato, Haruka Nishiwaki, Keiji Endo, Takashi Hayashi   +3 more
wiley   +1 more source

Reversible C-CN Bond Cleavage by a Formal Dinickel(I) Hydride Cation. [PDF]

Organometallics
Cao Y, Dodd NA, Bacsa J, Sadighi JP.
europepmc   +1 more source

SmI2‐Catalyzed Coupling of Alkyl Housane Ketones and Alkenes in an Approach to Norbornanes

Angewandte Chemie, EarlyView.
Samarium diiodide (Sml2) is an effective catalyst for the mild, atom‐economical coupling of bicyclo[2.1.0]pentane, or housane, ketones, and electron‐deficient alkenes to give functionalized norbornane structural motifs not easily accessible by classical cycloaddition approaches.
Debayan Roy, Jack I. Mansell, Giorgia Barison, Song Yu, Rocco Katavic, Ciro Romano, Nikolas Kaltsoyannis, David J. Procter   +7 more
wiley   +1 more source

Exploring advanced nanostructures and functional materials for efficient hydrogen storage: a theoretical investigation on mechanisms, adsorption process, and future directions. [PDF]

Front Chem
Jana G, Chattaraj PK.
europepmc   +1 more source

Ligand‐Enabled Chemo‐ and Regioselective Ir(I)‐Catalyzed Intermolecular Hydrocarbonation of Allenes: Access to Branched Products with All‐Carbon Quaternary Centers

Angewandte Chemie, EarlyView.
Ir(I) catalysts featuring the electron‐deficient bisphosphine ligand dFppe promote the hydrocarbonation of allenes with precise control over the selectivity to yield highly valuable branched products. This reaction is highly effective with C(3)‐dialkylcarboxamidepyrroles as well as with other C─H donors, such as furans and α,β‐unsaturated carboxamides.
Alejandro Rey, Andrés Arribas, José L. Mascareñas, Fernando López   +3 more
wiley   +1 more source

Toward Bimetallic Nanowire Arrays with Controlled Compositions Using Block Copolymer Films: The Interplay Between Metal Precursors

Angewandte Chemie, EarlyView.
Co‐impregnation of block copolymer films enables the creation of ordered arrays of bimetallic nanowires (NWs). The dependence of the NW composition on the feed revealed direct and indirect modes of mutual influence between the metal precursors stemming from the types of interactions involved.
Ofer Burg, Carmel Cohen, Roy Shenhar
wiley   +1 more source

Design and development of spectrophotometric enzymatic cyanide assays. [PDF]

Anal Bioanal Chem
Šťastná K, Martínková L, Rucká L, Křístková B, Příhodová R, Bojarová P, Pátek M.   +6 more
europepmc   +1 more source