Results 31 to 40 of about 82,507 (282)

Recent advances in the iron-catalyzed cycloaddition reactions [PDF]

open access: yes, 2012
The rapid generation of molecular in a relatively easy manner has made the cycloaddition reaction a powerful tool in the synthesis of different membered ring compounds.
Wang ChunXiang   +4 more
core   +1 more source

Synthesis and the Biological Activity of Phosphonylated 1,2,3-Triazolenaphthalimide Conjugates

open access: yesMolecules, 2016
A novel series of diethyl {4-[(5-substituted-1,3-dioxo-1H-benzo[de]isoquinolin-2(3H)-yl)-methyl]-1H-1,2,3-triazol-1-yl}alkylphosphonates designed as analogues of amonafide was synthesized.
Iwona E. Głowacka   +6 more
doaj   +1 more source

Cycloaddition of 4-Acyl-1H-pyrrole-2,3-diones Fused at [e]-Side and Cyanamides: Divergent Approach to 4H-1,3-Oxazines

open access: yesMolecules, 2022
4-Acyl-1H-pyrrole-2,3-diones fused at [e]-side with a heterocyclic moiety are suitable platforms for the development of a hetero-Diels–Alder-reaction-based, diversity-oriented approaches to series of skeletally diverse heterocycles.
Ekaterina E. Khramtsova   +3 more
doaj   +1 more source

Morpholine-mediated defluorinative cycloaddition of gem-difluoroalkenes and organic azides [PDF]

open access: yes, 2023
Here, we report the first transition-metal free defluorinative cycloaddition of gem-difluoroalkenes with organic azides in morpholine as a solvent to construct fully decorated morpholine substituted-1,2,3-triazoles.
Destinee, Manning   +4 more
core   +2 more sources

Synthetic Studies on Erythromycin Derivatives: Reactivity of the C12-21 Alkene

open access: yesMolecules, 2006
The reactivity of the C12-21 alkene of some erythromycin A derivatives was studied. This double bond was easily oxidized to the corresponding epoxide with excellent stereoselectivity. A single crystal X-ray structure showed that the epoxide moiety was on
Wei-Min Chen
doaj   +1 more source

Azomethine Ylides—Versatile Synthons for Pyrrolidinyl-Heterocyclic Compounds

open access: yesMolecules, 2023
Azomethine ylides are nitrogen-based three-atom components commonly used in [3+2]-cycloaddition reactions with various unsaturated 2π-electron components.
Siva S. Panda   +3 more
doaj   +1 more source

Synthesis of Bicyclic Isoxazoles and Isoxazolines via Intramolecular Nitrile Oxide Cycloaddition

open access: yesMolecules, 2015
An efficient and straight forward procedure for the syntheses of bicyclic isoxazole/isoxazoline derivatives from the corresponding dimethyl-2-(2-nitro-1-aryl/alkyl)-2-(prop-2-yn-1yl)malonates or dimethyl 2-allyl-2-(2-nitro-1-aryl/alkyl ethyl)malonate is ...
Wen-Chang Chen   +8 more
doaj   +1 more source

Crystal structure of trans-dichloridobis[N-(5,5-dimethyl-4,5-dihydro-3H-pyrrol-2-yl-κN)acetamide]palladium(II) dihydrate

open access: yesActa Crystallographica Section E: Crystallographic Communications, 2017
The title complex, [PdCl2(C8H14N2O)2]·2H2O, was obtained by N–O bond cleavage of the oxadiazoline rings of the trans-[dichlorido-bis(2,5,5-trimethyl-5,6,7,7a-tetrahydropyrrolo[1,2-b][1,2,4]oxadiazole-N1)]palladium(II) complex.
Jamal Lasri   +3 more
doaj   +1 more source

Electrochemical Synthesis of Isoxazoles and Isoxazolines via Anodic Oxidation of Oximes

open access: yesChemElectroChem, 2023
Isoxazol(in)es are widely featured structural motifs in natural products, agrochemicals, and pharmaceuticals. The first intermolecular approach for a direct electrochemical synthesis from readily available aldoximes is reported.
Silja Hofmann   +4 more
doaj   +1 more source

Overview of 1,5-Selective Click Reaction of Azides with Alkynes or Their Synthetic Equivalents

open access: yesMolecules, 2023
Nowadays, the click reaction of azides with alkynes has evolved rapidly and become one of the most efficient methods to synthesize 1,2,3-triazoles, which are an important class of N-containing heterocycles.
Yaqi Zhao   +3 more
doaj   +1 more source

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