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Dibenzonaphthyridinones: Heterocycle-to-Heterocycle Synthetic Strategies and Photophysical Studies [PDF]

open access: yesOrganic Letters, 2015
A heterocycle-to-heterocycle strategy is presented for the preparation of highly fluorescent and solvatochromic dibenzonaphthyridinones (DBNs) via methodology that leads to the formation of a tertiary, spiro-fused carbon center. A linear correlation between the results of photophysical experiments and time dependent density functional theory ...
Palazzo, Teresa A   +7 more
core   +9 more sources

A BNAlP-heterocycle

open access: yesChemical Communications
Combining a phosphaalumene with its lighter congener, an iminoborane afforded a species with a BNAlP heterocycle.
Tim Wellnitz   +3 more
openaire   +4 more sources

Application of Polyamines and Amino Acid Derivatives Based on 2-Azabicycloalkane Backbone in Enantioselective Aldol Reaction

open access: yesMolecules, 2021
Carbon–carbon bond forming reactions, such as aldol reaction and condensation, belong to extremely desired transformations as manifested by >25,000 entries in SciFinder.
Dominika Iwan   +2 more
doaj   +1 more source

12H-Dibenzo[d,g][1,2,3]triselenocin-12-ol

open access: yesMolbank, 2022
Reaction of diphenylmethanol (4) with n-butyllithium and subsequent treatment with selenium resulted in 12H-dibenzo[d,g][1,2,3]triselenocin-12-ol (5) comprising a novel heterocyclic ring system.
Marko Boskovic   +3 more
doaj   +1 more source

Reactions of 4H-1,2,6-Thiadiazine Sulfides

open access: yesMolbank, 2022
3,5-Dichloro-4H-1,2,6-thiadiazin-4-one reacts with benzo[d]thiazole-2-thiol (1 equiv) and triethylamine (1 equiv) to give 3-(benzo[d]thiazol-2-ylthio)-5-chloro-4H-1,2,6-thiadiazin-4-one in 71% yield.
Andreas S. Kalogirou   +1 more
doaj   +1 more source

Reaction of 4,5-Dichloro-1,2,3-dithiazolium Chloride with 2-(Phenylsulfonyl)acetonitrile

open access: yesMolbank, 2022
The reaction of 4,5-dichloro-1,2,3-dithiazolium chloride with 2-(phenylsulfonyl)acetonitrile (1 equiv) in the presence of pyridine (2 equiv) gave S-(3-chloro-5-cyanoisothiazol-4-yl)benzenesulfonothioate and (Z)-2-(4-chloro-5H-1,2,3-dithiazol-5-ylidene)-2-
Konstantinos Plakas   +3 more
doaj   +1 more source

Heterocyclic Electrochemistry: Renewable Electricity in the Construction of Heterocycles

open access: yesACS Omega, 2023
Numerous applications in the realm of biological exploration and drug synthesis can be found in heterocyclic chemistry, which is a vast subject. Many efforts have been developed to further improve the reaction conditions to access this interesting family to prevent employing hazardous ingredients.
Samina Aslam   +5 more
openaire   +4 more sources

Heterocycle–Heterocycle Strategies: (2-Nitrophenyl)isoxazole Precursors to 4‑Aminoquinolines, 1H‑Indoles, and Quinolin-4(1H)‑ones

open access: yes, 2016
Reductive heterocycle–heterocycle (heterocycle → heterocycle; H–H) transformations that give 4-aminoquinolines, 3-acylindoles, and quinolin-4(1H)-ones from 2-nitrophenyl substituted isoxazoles are reported. When this methodology is applied to 3,5-, 4,5-,
Keith C. Coffman (1968733)   +5 more
core   +5 more sources

2-Amino-5-chloro-1H-pyrrole-3,4-dicarbonitrile

open access: yesMolbank, 2021
The reaction of tetracyanoethylene (TCNE) with HCl (g) in the presence of Sn (1 equiv) and AcOH resulted in 2-amino-5-chloro-1H-pyrrole-3,4-dicarbonitrile in a 74% yield. The compound was fully characterized.
Andreas S. Kalogirou   +1 more
doaj   +1 more source

6,10-Dichloro-1-oxa-4,8-dithia-7,9-diazaspiro[4.5]deca-6,9-diene

open access: yesMolbank, 2022
Reaction of 3,4,4,5-tetrachloro-4H-1,2,6-thiadiazine with 2-mercaptoethan-1-ol (1 equiv.) gave 6,10-dichloro-1-oxa-4,8-dithia-7,9-diazaspiro[4.5]deca-6,9-diene in 12% yield. The compound was fully characterized.
Andreas S. Kalogirou   +1 more
doaj   +1 more source

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