Results 191 to 200 of about 73,410 (278)

Photolytic Hydrophosphination: Insights Into Catalyzed and Uncatalyzed Processes

Chemistry – A European Journal, EarlyView.
Catalyst‐free photolytic hydrophosphination is demonstrated for vinyl arenes and activated alkenes in polar protic (alcohol) solvents. These reactions appear to be closed‐shell, affirming that even ambient light can impact a reaction—a potentially broad influence on even mundane reactions.
Emma J. Finfer, Evelyn M. Kempf, Rory Waterman   +2 more
wiley   +1 more source

The Participation of 3,3,3-Trichloro-1-nitroprop-1-ene in the [3 + 2] Cycloaddition Reaction with Selected Nitrile N-Oxides in the Light of the Experimental and MEDT Quantum Chemical Study. [PDF]

Molecules, 2021
Zawadzińska K, Ríos-Gutiérrez M, Kula K, Woliński P, Mirosław B, Krawczyk T, Jasiński R.   +6 more
europepmc   +1 more source

Revisiting the synthesis of dimethyl carbonate from methanol and carbon dioxide

The Canadian Journal of Chemical Engineering, EarlyView.
Abstract The process for producing dimethyl carbonate (DMC) from carbon dioxide (CO2) and methanol is explored in this article. It provides an overview of the thermodynamics involved in DMC synthesis, discussing the challenges and potential solutions. The article highlights the reported use of catalysts and dehydrating agents to improve DMC yield and ...
Diego Alexander Santos Araque, Niloofar Mozaffari, Louis Fradette, Serge Kaliaguine   +3 more
wiley   +1 more source

Photosalient effect and reversible photochromic photoluminescence driven by cascade [2 + 2] cycloaddition reaction and water adsorption in a 0D hybrid metal halide. [PDF]

Chem Sci
Chen C, Li Z, Xiao Y, Ye C, Wei J, Zeng R, Pang Q, Luo B.   +7 more
europepmc   +1 more source

Learning Strategies from Nature's Blueprint to Cyclic Carbonate Synthesis

ChemSusChem, Volume 18, Issue 6, March 15, 2025.
The development of sustainable synthetic methods for cyclic carbonates draws inspiration from nature, focusing on eco‐friendly processes and renewable resources like CO2 and biomass. This review explore various CO2 activation mechanisms, green chemistry principles, and green catalysts.
Erika Saccullo, Vincenzo Patamia, Chiara Zagni, Antonio Rescifina, Giuseppe Floresta   +4 more
wiley   +1 more source

Titanium metal-organic frameworks for photocatalytic CO₂ conversion through a cycloaddition reaction. [PDF]

Nanoscale Adv
Kegere J, Alneyadi SS, Paz AP, Siddig LA, Alblooshi A, Alnaqbi MA, Alzamly A, Greish YE.   +7 more
europepmc   +1 more source

Photoreversible Polyurea Actuators With Spatiotemporal Control and Adaptive Mechanics

ENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
A light–thermal responsive polyurea network incorporating reversibly dimerizable anthracene units enables spatiotemporal modulation of cross‐linking density and nearly 400‐fold stiffness tuning. Integrating programmable anisotropy, photopatterning, self‐healing, and photowelding within a single framework, this bioinspired “one network–multifunction ...
Zhiwen Song, Wang Li, Xinru Guo, Rui Pu, Wenxin Wang, Yujun Cheng, Liang Shen, Fei Gao   +7 more
wiley   +1 more source

Correction: Investing in entropy: the strategy of cucurbit[n]urils to accelerate the intramolecular Diels-Alder cycloaddition reaction of tertiary furfuryl amines. [PDF]

Chem Sci
de la Vega-Hernández K, Suero MG, Ballester P.   +2 more
europepmc   +1 more source

Phenolate‐ and Alcoholate‐Based Chromium N‐Heterocyclic Carbene Complexes: Structural Peculiarities, Magnetometric and Electron Paramagnetic Resonance Study, and Catalytic Ethylene Oligomerization

European Journal of Inorganic Chemistry, EarlyView.
The first low‐oxidation (I/III) state chromium‐complex bearing a O‐chelating NHC ligand has been synthesized and structurally characterized by single‐crystal X‐ray analysis. The formation of the mixed‐valence species was further supported by SQUID magnetometry and high‐field electron paramagnetic resonance (EPR) spectroscopy.
Somnath Bhattacharya, Alexander Allgaier, Wolfgang Frey, Joris van Slageren, Michael R. Buchmeiser   +4 more
wiley   +1 more source

Masked Silylenes: Controlled Generation and Reactivity Under Thermal and Equilibrium Conditions

European Journal of Inorganic Chemistry, EarlyView.
This Review provides an overview of masked silylenes as bench‐stable precursors that release silylenes (R2Si:) under thermal activation or reversible equilibria. Precursor preparation, generation pathways, and characteristic reactivity are summarized, including trapping chemistry, reversible interconversions, insertion‐type processes, and small ...
Kei Ota, Kanata Miyahara, Norio Nakata
wiley   +1 more source